Treatment of real paracetamol wastewater by fenton process

The study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical...

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Main Authors: Dalgic Gamze, Turkdogan Ilter F., Yetilmezsoy Kaan, Kocak Emel
Format: Article
Language:English
Published: Association of the Chemical Engineers of Serbia 2017-01-01
Series:Chemical Industry and Chemical Engineering Quarterly
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdf
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author Dalgic Gamze
Turkdogan Ilter F.
Yetilmezsoy Kaan
Kocak Emel
author_facet Dalgic Gamze
Turkdogan Ilter F.
Yetilmezsoy Kaan
Kocak Emel
author_sort Dalgic Gamze
collection DOAJ
description The study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical oxygen demand (COD), total organic carbon (TOC), 5-day biological oxygen demand (BOD5), PCT, para-amino phenol (PAP) and aniline were removed, respectively. Changes in the concentrations of these parameters were also investigated for both oxidation and settling steps of Fenton process. It was found that COD and TOC were removed at the settling step (precipitation) whereas PCT, PAP and aniline were removed at the oxidation step. Mass balance calculations were also studied to show the mass distributions of COD in different phases (gas + foam, effluent and sludge). Fenton process was found as an effective method for the pretreatment of real PCT wastewater for discharging in a determined collective treatment plant.
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spelling doaj.art-0e05fe1329184582ac0ea4ff81ccd2c92022-12-22T03:23:31ZengAssociation of the Chemical Engineers of SerbiaChemical Industry and Chemical Engineering Quarterly1451-93722217-74342017-01-0123217718610.2298/CICEQ150831029D1451-93721600029DTreatment of real paracetamol wastewater by fenton processDalgic Gamze0Turkdogan Ilter F.1Yetilmezsoy Kaan2Kocak Emel3Yildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyThe study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical oxygen demand (COD), total organic carbon (TOC), 5-day biological oxygen demand (BOD5), PCT, para-amino phenol (PAP) and aniline were removed, respectively. Changes in the concentrations of these parameters were also investigated for both oxidation and settling steps of Fenton process. It was found that COD and TOC were removed at the settling step (precipitation) whereas PCT, PAP and aniline were removed at the oxidation step. Mass balance calculations were also studied to show the mass distributions of COD in different phases (gas + foam, effluent and sludge). Fenton process was found as an effective method for the pretreatment of real PCT wastewater for discharging in a determined collective treatment plant.http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdfchemical oxygen demandFenton processmass balancereal paracetamol wastewatertotal organic carbon
spellingShingle Dalgic Gamze
Turkdogan Ilter F.
Yetilmezsoy Kaan
Kocak Emel
Treatment of real paracetamol wastewater by fenton process
Chemical Industry and Chemical Engineering Quarterly
chemical oxygen demand
Fenton process
mass balance
real paracetamol wastewater
total organic carbon
title Treatment of real paracetamol wastewater by fenton process
title_full Treatment of real paracetamol wastewater by fenton process
title_fullStr Treatment of real paracetamol wastewater by fenton process
title_full_unstemmed Treatment of real paracetamol wastewater by fenton process
title_short Treatment of real paracetamol wastewater by fenton process
title_sort treatment of real paracetamol wastewater by fenton process
topic chemical oxygen demand
Fenton process
mass balance
real paracetamol wastewater
total organic carbon
url http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdf
work_keys_str_mv AT dalgicgamze treatmentofrealparacetamolwastewaterbyfentonprocess
AT turkdoganilterf treatmentofrealparacetamolwastewaterbyfentonprocess
AT yetilmezsoykaan treatmentofrealparacetamolwastewaterbyfentonprocess
AT kocakemel treatmentofrealparacetamolwastewaterbyfentonprocess