Treatment of real paracetamol wastewater by fenton process
The study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical...
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Format: | Article |
Language: | English |
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Association of the Chemical Engineers of Serbia
2017-01-01
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Series: | Chemical Industry and Chemical Engineering Quarterly |
Subjects: | |
Online Access: | http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdf |
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author | Dalgic Gamze Turkdogan Ilter F. Yetilmezsoy Kaan Kocak Emel |
author_facet | Dalgic Gamze Turkdogan Ilter F. Yetilmezsoy Kaan Kocak Emel |
author_sort | Dalgic Gamze |
collection | DOAJ |
description | The study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical oxygen demand (COD), total organic carbon (TOC), 5-day biological oxygen demand (BOD5), PCT, para-amino phenol (PAP) and aniline were removed, respectively. Changes in the concentrations of these parameters were also investigated for both oxidation and settling steps of Fenton process. It was found that COD and TOC were removed at the settling step (precipitation) whereas PCT, PAP and aniline were removed at the oxidation step. Mass balance calculations were also studied to show the mass distributions of COD in different phases (gas + foam, effluent and sludge). Fenton process was found as an effective method for the pretreatment of real PCT wastewater for discharging in a determined collective treatment plant. |
first_indexed | 2024-04-12T17:19:26Z |
format | Article |
id | doaj.art-0e05fe1329184582ac0ea4ff81ccd2c9 |
institution | Directory Open Access Journal |
issn | 1451-9372 2217-7434 |
language | English |
last_indexed | 2024-04-12T17:19:26Z |
publishDate | 2017-01-01 |
publisher | Association of the Chemical Engineers of Serbia |
record_format | Article |
series | Chemical Industry and Chemical Engineering Quarterly |
spelling | doaj.art-0e05fe1329184582ac0ea4ff81ccd2c92022-12-22T03:23:31ZengAssociation of the Chemical Engineers of SerbiaChemical Industry and Chemical Engineering Quarterly1451-93722217-74342017-01-0123217718610.2298/CICEQ150831029D1451-93721600029DTreatment of real paracetamol wastewater by fenton processDalgic Gamze0Turkdogan Ilter F.1Yetilmezsoy Kaan2Kocak Emel3Yildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyYildiz Technical University, Faculty of Civil Engineering, Department of Environmental Engineering, Davutpasa, Esenler, Istanbul, TurkeyThe study investigated the pretreatment of real paracetamol (PCT) wastewater of a pharmaceutical industry by Fenton process. At the best experimental conditions (COD/H2O2 = 1/1, Fe+2/H2O2 = 1/70, settling method:centrifuging, pH 6 at settling step), 92.7, 92.7, 95.5, 99.1, 99.9 and 99.4% of chemical oxygen demand (COD), total organic carbon (TOC), 5-day biological oxygen demand (BOD5), PCT, para-amino phenol (PAP) and aniline were removed, respectively. Changes in the concentrations of these parameters were also investigated for both oxidation and settling steps of Fenton process. It was found that COD and TOC were removed at the settling step (precipitation) whereas PCT, PAP and aniline were removed at the oxidation step. Mass balance calculations were also studied to show the mass distributions of COD in different phases (gas + foam, effluent and sludge). Fenton process was found as an effective method for the pretreatment of real PCT wastewater for discharging in a determined collective treatment plant.http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdfchemical oxygen demandFenton processmass balancereal paracetamol wastewatertotal organic carbon |
spellingShingle | Dalgic Gamze Turkdogan Ilter F. Yetilmezsoy Kaan Kocak Emel Treatment of real paracetamol wastewater by fenton process Chemical Industry and Chemical Engineering Quarterly chemical oxygen demand Fenton process mass balance real paracetamol wastewater total organic carbon |
title | Treatment of real paracetamol wastewater by fenton process |
title_full | Treatment of real paracetamol wastewater by fenton process |
title_fullStr | Treatment of real paracetamol wastewater by fenton process |
title_full_unstemmed | Treatment of real paracetamol wastewater by fenton process |
title_short | Treatment of real paracetamol wastewater by fenton process |
title_sort | treatment of real paracetamol wastewater by fenton process |
topic | chemical oxygen demand Fenton process mass balance real paracetamol wastewater total organic carbon |
url | http://www.doiserbia.nb.rs/img/doi/1451-9372/2017/1451-93721600029D.pdf |
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