Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties

Complex inorganic powders based on calcium phosphates have found a plethora of practical applications. Of particular interest are the CaO-P<sub>2</sub>O<sub>5</sub> system-based multi-component material powders and granules as the source of major- and micronutrients for the p...

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Main Authors: Mohamed Ammar, Sherif Ashraf, Jonas Baltrusaitis
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Ceramics
Subjects:
Online Access:https://www.mdpi.com/2571-6131/6/3/110
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author Mohamed Ammar
Sherif Ashraf
Jonas Baltrusaitis
author_facet Mohamed Ammar
Sherif Ashraf
Jonas Baltrusaitis
author_sort Mohamed Ammar
collection DOAJ
description Complex inorganic powders based on calcium phosphates have found a plethora of practical applications. Of particular interest are the CaO-P<sub>2</sub>O<sub>5</sub> system-based multi-component material powders and granules as the source of major- and micronutrients for the plants. The emerging strategy is to use nano fertilizers based on hydroxyapatite (HAP) for phosphorus and other nutrient delivery. The doping of micronutrients into HAP structure presents an interesting challenge in obtaining specific phase compositions of these calcium phosphates. Various techniques, including mechanochemical synthesis, have been employed to fabricate doped HAP. Mechanochemical synthesis is of particular interest in this review since it presents a relatively simple, scalable, and cost-effective method of calcium phosphate powder processing. The method involves the use of mechanical force to promote chemical reactions and create nanometric powders. This technique has been successfully applied to produce HAP nanoparticles alone, and HAP doped with other elements, such as zinc and magnesium. Nanofertilizers developed through mechanochemical synthesis can offer several advantages over conventional fertilizers. Their nanoscale size allows for rapid absorption and controlled release of nutrients, which leads to improved nutrient uptake efficiency by plants. Furthermore, the tailored properties of HAP-based nano fertilizers, such as controlled porosity and degradation levels, contribute to their effectiveness in providing plant nutrition.
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spelling doaj.art-0e0fe85dcee1481f9400e01ade8694972023-11-19T10:00:58ZengMDPI AGCeramics2571-61312023-08-01631799182510.3390/ceramics6030110Nutrient-Doped Hydroxyapatite: Structure, Synthesis and PropertiesMohamed Ammar0Sherif Ashraf1Jonas Baltrusaitis2Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, PA 18015, USADepartment of Physics, Faculty of Science, Suez University, Suez 43518, EgyptDepartment of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, PA 18015, USAComplex inorganic powders based on calcium phosphates have found a plethora of practical applications. Of particular interest are the CaO-P<sub>2</sub>O<sub>5</sub> system-based multi-component material powders and granules as the source of major- and micronutrients for the plants. The emerging strategy is to use nano fertilizers based on hydroxyapatite (HAP) for phosphorus and other nutrient delivery. The doping of micronutrients into HAP structure presents an interesting challenge in obtaining specific phase compositions of these calcium phosphates. Various techniques, including mechanochemical synthesis, have been employed to fabricate doped HAP. Mechanochemical synthesis is of particular interest in this review since it presents a relatively simple, scalable, and cost-effective method of calcium phosphate powder processing. The method involves the use of mechanical force to promote chemical reactions and create nanometric powders. This technique has been successfully applied to produce HAP nanoparticles alone, and HAP doped with other elements, such as zinc and magnesium. Nanofertilizers developed through mechanochemical synthesis can offer several advantages over conventional fertilizers. Their nanoscale size allows for rapid absorption and controlled release of nutrients, which leads to improved nutrient uptake efficiency by plants. Furthermore, the tailored properties of HAP-based nano fertilizers, such as controlled porosity and degradation levels, contribute to their effectiveness in providing plant nutrition.https://www.mdpi.com/2571-6131/6/3/110hydroxyapatitefertilizermechanochemistrydopantnutrients
spellingShingle Mohamed Ammar
Sherif Ashraf
Jonas Baltrusaitis
Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
Ceramics
hydroxyapatite
fertilizer
mechanochemistry
dopant
nutrients
title Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
title_full Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
title_fullStr Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
title_full_unstemmed Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
title_short Nutrient-Doped Hydroxyapatite: Structure, Synthesis and Properties
title_sort nutrient doped hydroxyapatite structure synthesis and properties
topic hydroxyapatite
fertilizer
mechanochemistry
dopant
nutrients
url https://www.mdpi.com/2571-6131/6/3/110
work_keys_str_mv AT mohamedammar nutrientdopedhydroxyapatitestructuresynthesisandproperties
AT sherifashraf nutrientdopedhydroxyapatitestructuresynthesisandproperties
AT jonasbaltrusaitis nutrientdopedhydroxyapatitestructuresynthesisandproperties