Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance
Localized surface plasmon-induced photoreactions at metal nanostructures have become central research topics in biology, catalysis, and analytical chemistry. In particular, the decomposition of organic pollutants is a popular topic. Rhodamine B is useful in the dye industry and biology; however, it...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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AIP Publishing LLC
2019-03-01
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| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/1.5093763 |
| _version_ | 1818430764957564928 |
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| author | Satoshi Kaneko Shuhei Watanabe Shinya Kasai Tomoaki Nishino Kazuhito Tsukagoshi Manabu Kiguchi |
| author_facet | Satoshi Kaneko Shuhei Watanabe Shinya Kasai Tomoaki Nishino Kazuhito Tsukagoshi Manabu Kiguchi |
| author_sort | Satoshi Kaneko |
| collection | DOAJ |
| description | Localized surface plasmon-induced photoreactions at metal nanostructures have become central research topics in biology, catalysis, and analytical chemistry. In particular, the decomposition of organic pollutants is a popular topic. Rhodamine B is useful in the dye industry and biology; however, it is harmful to humans and the environment. In this study, we investigated the decomposition of the Rhodamine B molecule with a structurally well-defined array of gold square dimers. The array of gold square dimers was fabricated by electron beam lithography, which provided a homogenous well-defined reaction field. Continuous Raman spectral measurements using a near-infrared laser clearly showed that while the Rhodamine B molecules were stable in the absence of the gold square dimers, they were decomposed under near-infrared-light irradiation. |
| first_indexed | 2024-12-14T15:38:36Z |
| format | Article |
| id | doaj.art-0e1ea1e1f82d439ea3761c9f0e52e15f |
| institution | Directory Open Access Journal |
| issn | 2158-3226 |
| language | English |
| last_indexed | 2024-12-14T15:38:36Z |
| publishDate | 2019-03-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | AIP Advances |
| spelling | doaj.art-0e1ea1e1f82d439ea3761c9f0e52e15f2022-12-21T22:55:40ZengAIP Publishing LLCAIP Advances2158-32262019-03-0193035153035153-510.1063/1.5093763106903ADVNear-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distanceSatoshi Kaneko0Shuhei Watanabe1Shinya Kasai2Tomoaki Nishino3Kazuhito Tsukagoshi4Manabu Kiguchi5Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 W4-10 Ookayama, Meguro-ku, Tokyo 152-8551, JapanDepartment of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 W4-10 Ookayama, Meguro-ku, Tokyo 152-8551, JapanJST, Presto 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, JapanDepartment of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 W4-10 Ookayama, Meguro-ku, Tokyo 152-8551, JapanInternational Center for Materials Nanoarchitectonics, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, JapanDepartment of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 W4-10 Ookayama, Meguro-ku, Tokyo 152-8551, JapanLocalized surface plasmon-induced photoreactions at metal nanostructures have become central research topics in biology, catalysis, and analytical chemistry. In particular, the decomposition of organic pollutants is a popular topic. Rhodamine B is useful in the dye industry and biology; however, it is harmful to humans and the environment. In this study, we investigated the decomposition of the Rhodamine B molecule with a structurally well-defined array of gold square dimers. The array of gold square dimers was fabricated by electron beam lithography, which provided a homogenous well-defined reaction field. Continuous Raman spectral measurements using a near-infrared laser clearly showed that while the Rhodamine B molecules were stable in the absence of the gold square dimers, they were decomposed under near-infrared-light irradiation.http://dx.doi.org/10.1063/1.5093763 |
| spellingShingle | Satoshi Kaneko Shuhei Watanabe Shinya Kasai Tomoaki Nishino Kazuhito Tsukagoshi Manabu Kiguchi Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance AIP Advances |
| title | Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance |
| title_full | Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance |
| title_fullStr | Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance |
| title_full_unstemmed | Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance |
| title_short | Near-infrared-light-induced decomposition of Rhodamine B triggered by localized surface plasmon at gold square dimers with well-defined separation distance |
| title_sort | near infrared light induced decomposition of rhodamine b triggered by localized surface plasmon at gold square dimers with well defined separation distance |
| url | http://dx.doi.org/10.1063/1.5093763 |
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