INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE)
This work aims to develop and characterize blends of thermoplastic starch (TPS) modified with citric acid and poly(butylene-adipate-co-terephthalate) (PBAT), using sweet potato (SP) and cassava (C) as starch sources. The blends were produced through extrusion, combining thermoplastic starch with PBA...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2024-06-01
|
Series: | Carbohydrate Polymer Technologies and Applications |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2666893924000136 |
_version_ | 1797322401559609344 |
---|---|
author | Ingrid A. dos S. Matusinho Thaís F. Ramos Jhonatan B. de Oliveira Emerson F. Pedroso Patterson P. de Souza Patrícia S. de O. Patricio |
author_facet | Ingrid A. dos S. Matusinho Thaís F. Ramos Jhonatan B. de Oliveira Emerson F. Pedroso Patterson P. de Souza Patrícia S. de O. Patricio |
author_sort | Ingrid A. dos S. Matusinho |
collection | DOAJ |
description | This work aims to develop and characterize blends of thermoplastic starch (TPS) modified with citric acid and poly(butylene-adipate-co-terephthalate) (PBAT), using sweet potato (SP) and cassava (C) as starch sources. The blends were produced through extrusion, combining thermoplastic starch with PBAT, and characterized using Infrared Absorption Spectroscopy, X-ray diffraction, a scanning electron microscope, tensile testing, and swelling analyses. The starch granules from SP and C showed variations in structure and composition (specifically in the amylose-to-amylopectin ratio), influencing the morphology and properties of the blends. The TPS-SP/PBAT blends exhibited greater resistance and lower hydrophilicity compared to the TPS-C/PBAT blends. Variations in the properties of the blends were also observed with different amounts of the biodegradable polyester used. The developed blends offer a long-term sustainable alternative to conventional polymers in the manufacturing of disposable packaging for the food industry. |
first_indexed | 2024-03-08T05:13:47Z |
format | Article |
id | doaj.art-0e28050ab5054737803ce39b196d25f4 |
institution | Directory Open Access Journal |
issn | 2666-8939 |
language | English |
last_indexed | 2024-03-08T05:13:47Z |
publishDate | 2024-06-01 |
publisher | Elsevier |
record_format | Article |
series | Carbohydrate Polymer Technologies and Applications |
spelling | doaj.art-0e28050ab5054737803ce39b196d25f42024-02-07T04:46:01ZengElsevierCarbohydrate Polymer Technologies and Applications2666-89392024-06-017100433INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE)Ingrid A. dos S. Matusinho0Thaís F. Ramos1Jhonatan B. de Oliveira2Emerson F. Pedroso3Patterson P. de Souza4Patrícia S. de O. Patricio5Chemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilChemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilChemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilChemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilChemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilCorresponidng author.; Chemistry Departament, Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169, BH-MG, BrazilThis work aims to develop and characterize blends of thermoplastic starch (TPS) modified with citric acid and poly(butylene-adipate-co-terephthalate) (PBAT), using sweet potato (SP) and cassava (C) as starch sources. The blends were produced through extrusion, combining thermoplastic starch with PBAT, and characterized using Infrared Absorption Spectroscopy, X-ray diffraction, a scanning electron microscope, tensile testing, and swelling analyses. The starch granules from SP and C showed variations in structure and composition (specifically in the amylose-to-amylopectin ratio), influencing the morphology and properties of the blends. The TPS-SP/PBAT blends exhibited greater resistance and lower hydrophilicity compared to the TPS-C/PBAT blends. Variations in the properties of the blends were also observed with different amounts of the biodegradable polyester used. The developed blends offer a long-term sustainable alternative to conventional polymers in the manufacturing of disposable packaging for the food industry.http://www.sciencedirect.com/science/article/pii/S2666893924000136Blendsthermoplastic starchPoly(Butylene-Adipate-Co-Terephthalate)Swelling |
spellingShingle | Ingrid A. dos S. Matusinho Thaís F. Ramos Jhonatan B. de Oliveira Emerson F. Pedroso Patterson P. de Souza Patrícia S. de O. Patricio INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) Carbohydrate Polymer Technologies and Applications Blends thermoplastic starch Poly(Butylene-Adipate-Co-Terephthalate) Swelling |
title | INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) |
title_full | INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) |
title_fullStr | INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) |
title_full_unstemmed | INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) |
title_short | INFLUENCE OF STARCH SOURCE ON PROPERTIES OF BLENDS BASED ON THERMOPLASTIC STARCH AND POLY(BUTYLENE-ADIPATE-CO-TEREPHTHALATE) |
title_sort | influence of starch source on properties of blends based on thermoplastic starch and poly butylene adipate co terephthalate |
topic | Blends thermoplastic starch Poly(Butylene-Adipate-Co-Terephthalate) Swelling |
url | http://www.sciencedirect.com/science/article/pii/S2666893924000136 |
work_keys_str_mv | AT ingridadossmatusinho influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate AT thaisframos influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate AT jhonatanbdeoliveira influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate AT emersonfpedroso influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate AT pattersonpdesouza influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate AT patriciasdeopatricio influenceofstarchsourceonpropertiesofblendsbasedonthermoplasticstarchandpolybutyleneadipatecoterephthalate |