Crystalquasichemical Description the Formation of Defects in nanodispersed Yttrium-Iron Garnet
<p>By the sol-gel method of autocombustionan initial oxide system was synthesized for a receipt a nanodispersed Yttrium Iron Garnet. It was set that forming of the monophase system Y<sub>3</sub>Fe<sub>5</sub>O<sub>12<...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Vasyl Stefanyk Precarpathian National University
2017-09-01
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| Series: | Фізика і хімія твердого тіла |
| Online Access: | http://journals.pu.if.ua/index.php/pcss/article/view/1252 |
| Summary: | <p>By the sol-gel method of autocombustionan initial oxide system was synthesized for a receipt a nanodispersed Yttrium Iron Garnet. It was set that forming of the monophase system Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub>begins at temperatures above 973 К in static air atmosphere. The crystalquasichemical formulas for Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub> are offered. Dependence of concentration of defects from a degree non-stoichiometry of oxygen is calculated. It was set that the formation of garnet structure needed oxygen atmosphere annealing. Partial pressure of oxygen determines the resulting structure defects.</p><p><strong>Keywords:</strong> yttrium iron garnet, sol-gel-autocombustion method, isothermal annealing, atmosphere, crystalquasichemical formulas, defects.</p> |
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| ISSN: | 1729-4428 2309-8589 |