Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups
Sorption processes of noble metals on silica gel surface with covalently grafted N- (5-mercapto-1,3,4-thiadiazol-2-yl)- N '-propylurea groups (MTS) were studied. It was found that sorption onto MTS may occur via complexation and/or anion-exchange mechanisms depending on the acidity of the solut...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
2007-02-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/026361707781485735 |
| _version_ | 1797284404770373632 |
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| author | A.K. Trokhimchuk I.M. Boychenko V.N. Losev |
| author_facet | A.K. Trokhimchuk I.M. Boychenko V.N. Losev |
| author_sort | A.K. Trokhimchuk |
| collection | DOAJ |
| description | Sorption processes of noble metals on silica gel surface with covalently grafted N- (5-mercapto-1,3,4-thiadiazol-2-yl)- N '-propylurea groups (MTS) were studied. It was found that sorption onto MTS may occur via complexation and/or anion-exchange mechanisms depending on the acidity of the solutions. It was shown that differences in the kinetics and temperature conditions for the sorption of platinum and gold can be used to separate micro-amounts of these metals in solution. |
| first_indexed | 2024-03-07T17:48:30Z |
| format | Article |
| id | doaj.art-0e373e487f954627a80aea72437d1a4a |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:48:30Z |
| publishDate | 2007-02-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-0e373e487f954627a80aea72437d1a4a2024-03-02T14:27:26ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382007-02-012510.1260/026361707781485735Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea GroupsA.K. Trokhimchuk0I.M. Boychenko1V.N. Losev2 Kiev National Taras Shevchenko University. 64 Volodymyrska Str., 01033 Kiev, Ukraine Kiev National Taras Shevchenko University. 64 Volodymyrska Str., 01033 Kiev, Ukraine “Crystal” Research Centre, 79 Svobodnyi Pr., 660041 Krasnoyarsk, RussiaSorption processes of noble metals on silica gel surface with covalently grafted N- (5-mercapto-1,3,4-thiadiazol-2-yl)- N '-propylurea groups (MTS) were studied. It was found that sorption onto MTS may occur via complexation and/or anion-exchange mechanisms depending on the acidity of the solutions. It was shown that differences in the kinetics and temperature conditions for the sorption of platinum and gold can be used to separate micro-amounts of these metals in solution.https://doi.org/10.1260/026361707781485735 |
| spellingShingle | A.K. Trokhimchuk I.M. Boychenko V.N. Losev Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups Adsorption Science & Technology |
| title | Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups |
| title_full | Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups |
| title_fullStr | Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups |
| title_full_unstemmed | Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups |
| title_short | Sorption of Noble Metals on Silica Gel Chemically Modified with -(5-Mercapto-1,3,4-Thiadiazol-2-yl)-'-Propylurea Groups |
| title_sort | sorption of noble metals on silica gel chemically modified with 5 mercapto 1 3 4 thiadiazol 2 yl propylurea groups |
| url | https://doi.org/10.1260/026361707781485735 |
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