Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode
A versatile strategy for electrochemical determination of glycoalkaloids (GAs) was developed by using a carbon nanotubes-phenylboronic acid (CNTs-PBA) modified glassy carbon electrode. PBA reacts with α-solanine and α-chaconine to form a cyclic ester, which could be utilized to detect GAs. This meth...
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MDPI AG
2013-11-01
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Series: | Sensors |
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Online Access: | http://www.mdpi.com/1424-8220/13/12/16234 |
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author | Huiying Wang Mingyue Liu Xinxi Hu Mei Li Xingyao Xiong |
author_facet | Huiying Wang Mingyue Liu Xinxi Hu Mei Li Xingyao Xiong |
author_sort | Huiying Wang |
collection | DOAJ |
description | A versatile strategy for electrochemical determination of glycoalkaloids (GAs) was developed by using a carbon nanotubes-phenylboronic acid (CNTs-PBA) modified glassy carbon electrode. PBA reacts with α-solanine and α-chaconine to form a cyclic ester, which could be utilized to detect GAs. This method allowed GA detection from 1 μM to 28 μM and the detection limit was 0.3 μM. Affinity interaction of GAs and immobilized PBA caused an essential change of the peak current. The CNT-PBA modified electrodes were sensitive for detection of GAs, and the peak current values were in quite good agreement with those measured by the sensors. |
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id | doaj.art-0e410ec694df4539aa38046c4b209e47 |
institution | Directory Open Access Journal |
issn | 1424-8220 |
language | English |
last_indexed | 2024-04-11T13:59:56Z |
publishDate | 2013-11-01 |
publisher | MDPI AG |
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series | Sensors |
spelling | doaj.art-0e410ec694df4539aa38046c4b209e472022-12-22T04:20:09ZengMDPI AGSensors1424-82202013-11-011312162341624410.3390/s131216234s131216234Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon ElectrodeHuiying Wang0Mingyue Liu1Xinxi Hu2Mei Li3Xingyao Xiong4College of Horticulture and Landscape, Hunan Agriculture University, Changsha 410128, ChinaCollege of Horticulture and Landscape, Hunan Agriculture University, Changsha 410128, ChinaCollege of Horticulture and Landscape, Hunan Agriculture University, Changsha 410128, ChinaCollege of Horticulture and Landscape, Hunan Agriculture University, Changsha 410128, ChinaCollege of Horticulture and Landscape, Hunan Agriculture University, Changsha 410128, ChinaA versatile strategy for electrochemical determination of glycoalkaloids (GAs) was developed by using a carbon nanotubes-phenylboronic acid (CNTs-PBA) modified glassy carbon electrode. PBA reacts with α-solanine and α-chaconine to form a cyclic ester, which could be utilized to detect GAs. This method allowed GA detection from 1 μM to 28 μM and the detection limit was 0.3 μM. Affinity interaction of GAs and immobilized PBA caused an essential change of the peak current. The CNT-PBA modified electrodes were sensitive for detection of GAs, and the peak current values were in quite good agreement with those measured by the sensors.http://www.mdpi.com/1424-8220/13/12/16234carbon nanotubesphenylboronic acidglycoalkaloidssensor |
spellingShingle | Huiying Wang Mingyue Liu Xinxi Hu Mei Li Xingyao Xiong Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode Sensors carbon nanotubes phenylboronic acid glycoalkaloids sensor |
title | Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode |
title_full | Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode |
title_fullStr | Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode |
title_full_unstemmed | Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode |
title_short | Electrochemical Determination of Glycoalkaloids Using a Carbon Nanotubes-Phenylboronic Acid Modified Glassy Carbon Electrode |
title_sort | electrochemical determination of glycoalkaloids using a carbon nanotubes phenylboronic acid modified glassy carbon electrode |
topic | carbon nanotubes phenylboronic acid glycoalkaloids sensor |
url | http://www.mdpi.com/1424-8220/13/12/16234 |
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