Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes

The amorphous LiPON thin film was obtained by using the crystalline Li3PO4 target and the RF magnetron sputtering method at a N2 working pressure of 1 Pa. and then the morphology and composition of LiPON thin films are analysed by SEM and EDS. SEM shows that the film was compact and smooth, while ED...

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Main Authors: Tan Feihu, Liang XiaoPing, Wei Feng, Du Jun
Format: Article
Language:English
Published: EDP Sciences 2018-01-01
Series:E3S Web of Conferences
Online Access:https://doi.org/10.1051/e3sconf/20185301008
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author Tan Feihu
Liang XiaoPing
Wei Feng
Du Jun
author_facet Tan Feihu
Liang XiaoPing
Wei Feng
Du Jun
author_sort Tan Feihu
collection DOAJ
description The amorphous LiPON thin film was obtained by using the crystalline Li3PO4 target and the RF magnetron sputtering method at a N2 working pressure of 1 Pa. and then the morphology and composition of LiPON thin films are analysed by SEM and EDS. SEM shows that the film was compact and smooth, while EDS shows that the content of N in LiPON thin film was about 17.47%. The electrochemical properties of Pt/LiPON/Pt were analysed by EIS, and the ionic conductivity of LiPON thin films was 3.8×10-7 S/cm. By using the hard mask in the magnetron sputtering process, the all-solid-state thin film battery with Si/Ti/Pt/LiCoO2/LiPON/Li4Ti5O12/Pt structure was prepared, and its electrical properties were studied. As for this thin film battery, the open circuit voltage was 1.9 V and the first discharge specific capacity was 34.7 μAh/cm2·μm at a current density of 5 μA/cm-2, indicating that is promising in all-solidstate thin film batteries.
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spelling doaj.art-0e414b69c8da4e169b7aaaf768cabb502022-12-21T22:11:33ZengEDP SciencesE3S Web of Conferences2267-12422018-01-01530100810.1051/e3sconf/20185301008e3sconf_icaeer2018_01008Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for ElectrolytesTan FeihuLiang XiaoPingWei FengDu JunThe amorphous LiPON thin film was obtained by using the crystalline Li3PO4 target and the RF magnetron sputtering method at a N2 working pressure of 1 Pa. and then the morphology and composition of LiPON thin films are analysed by SEM and EDS. SEM shows that the film was compact and smooth, while EDS shows that the content of N in LiPON thin film was about 17.47%. The electrochemical properties of Pt/LiPON/Pt were analysed by EIS, and the ionic conductivity of LiPON thin films was 3.8×10-7 S/cm. By using the hard mask in the magnetron sputtering process, the all-solid-state thin film battery with Si/Ti/Pt/LiCoO2/LiPON/Li4Ti5O12/Pt structure was prepared, and its electrical properties were studied. As for this thin film battery, the open circuit voltage was 1.9 V and the first discharge specific capacity was 34.7 μAh/cm2·μm at a current density of 5 μA/cm-2, indicating that is promising in all-solidstate thin film batteries.https://doi.org/10.1051/e3sconf/20185301008
spellingShingle Tan Feihu
Liang XiaoPing
Wei Feng
Du Jun
Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
E3S Web of Conferences
title Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
title_full Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
title_fullStr Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
title_full_unstemmed Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
title_short Fabrication and Testing of All-solid-state Nanoscale Lithium Batteries Using LiPON for Electrolytes
title_sort fabrication and testing of all solid state nanoscale lithium batteries using lipon for electrolytes
url https://doi.org/10.1051/e3sconf/20185301008
work_keys_str_mv AT tanfeihu fabricationandtestingofallsolidstatenanoscalelithiumbatteriesusingliponforelectrolytes
AT liangxiaoping fabricationandtestingofallsolidstatenanoscalelithiumbatteriesusingliponforelectrolytes
AT weifeng fabricationandtestingofallsolidstatenanoscalelithiumbatteriesusingliponforelectrolytes
AT dujun fabricationandtestingofallsolidstatenanoscalelithiumbatteriesusingliponforelectrolytes