4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide
The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H...N hydrogen bonds, between the sulfonamide nitrogen-H atom and the azomethine N atom, link the molecules into inversion dimers, formin...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814012136 |
| _version_ | 1818998720175276032 |
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| author | Mustafa Durgun Hasan Türkmen Tuncay Tunç Tuncer Hökelek |
| author_facet | Mustafa Durgun Hasan Türkmen Tuncay Tunç Tuncer Hökelek |
| author_sort | Mustafa Durgun |
| collection | DOAJ |
| description | The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H...N hydrogen bonds, between the sulfonamide nitrogen-H atom and the azomethine N atom, link the molecules into inversion dimers, forming R22(16) ring motifs. These dimers are linked by N—H...O hydrogen bonds, between the sulfonamide nitrogen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped π–π interactions involving inversion-related benzenesulfonamide rings [centroid–centroid distance = 3.8800 (9) Å; normal distance = 3.4796 (6) Å; slippage = 1.717 Å]. |
| first_indexed | 2024-12-20T22:06:00Z |
| format | Article |
| id | doaj.art-0e44b797c849458090211904dae961a7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:06:00Z |
| publishDate | 2014-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0e44b797c849458090211904dae961a72022-12-21T19:25:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706o726o72710.1107/S1600536814012136su27384-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamideMustafa Durgun0Hasan Türkmen1Tuncay Tunç2Tuncer Hökelek3Department of Chemistry, Harran University, 63300 Şanlıurfa, TurkeyDepartment of Chemistry, Harran University, 63300 Şanlıurfa, TurkeyScience Education Department, Aksaray University, 68100 Aksaray, TurkeyDepartment of Physics, Hacettepe University, 06800 Beytepe, Ankara, TurkeyThe title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H...N hydrogen bonds, between the sulfonamide nitrogen-H atom and the azomethine N atom, link the molecules into inversion dimers, forming R22(16) ring motifs. These dimers are linked by N—H...O hydrogen bonds, between the sulfonamide nitrogen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped π–π interactions involving inversion-related benzenesulfonamide rings [centroid–centroid distance = 3.8800 (9) Å; normal distance = 3.4796 (6) Å; slippage = 1.717 Å].http://scripts.iucr.org/cgi-bin/paper?S1600536814012136 |
| spellingShingle | Mustafa Durgun Hasan Türkmen Tuncay Tunç Tuncer Hökelek 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide Acta Crystallographica Section E |
| title | 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide |
| title_full | 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide |
| title_fullStr | 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide |
| title_full_unstemmed | 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide |
| title_short | 4-{[4-(Dimethylamino)benzylidene]amino}benzenesulfonamide |
| title_sort | 4 4 dimethylamino benzylidene amino benzenesulfonamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814012136 |
| work_keys_str_mv | AT mustafadurgun 44dimethylaminobenzylideneaminobenzenesulfonamide AT hasanturkmen 44dimethylaminobenzylideneaminobenzenesulfonamide AT tuncaytunc 44dimethylaminobenzylideneaminobenzenesulfonamide AT tuncerhokelek 44dimethylaminobenzylideneaminobenzenesulfonamide |