Excessively High Vapor Pressure of Al-based Amorphous Alloys

Aluminum-based amorphous alloys exhibited an abnormally high vapor pressure at their approximate glass transition temperatures. The vapor pressure was confirmed by the formation of Al nanocrystallites from condensation, which was attributed to weight loss of the amorphous alloys. The amount of w...

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Main Authors: Jae Im Jeong, Sung Hyuk Lee, Je-Beom Jeon, Suk Jun Kim
Format: Article
Language:English
Published: MDPI AG 2015-10-01
Series:Metals
Subjects:
Online Access:http://www.mdpi.com/2075-4701/5/4/1878
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author Jae Im Jeong
Sung Hyuk Lee
Je-Beom Jeon
Suk Jun Kim
author_facet Jae Im Jeong
Sung Hyuk Lee
Je-Beom Jeon
Suk Jun Kim
author_sort Jae Im Jeong
collection DOAJ
description Aluminum-based amorphous alloys exhibited an abnormally high vapor pressure at their approximate glass transition temperatures. The vapor pressure was confirmed by the formation of Al nanocrystallites from condensation, which was attributed to weight loss of the amorphous alloys. The amount of weight loss varied with the amorphous alloy compositions and was inversely proportional to their glass-forming ability. The vapor pressure of the amorphous alloys around 573 K was close to the vapor pressure of crystalline Al near its melting temperature, 873 K. Our results strongly suggest the possibility of fabricating nanocrystallites or thin films by evaporation at low temperatures.
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spelling doaj.art-0e49afbcfa2f4c638d6dc84646fb4abc2022-12-22T00:50:25ZengMDPI AGMetals2075-47012015-10-01541878188610.3390/met5041878met5041878Excessively High Vapor Pressure of Al-based Amorphous AlloysJae Im Jeong0Sung Hyuk Lee1Je-Beom Jeon2Suk Jun Kim3School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education (KOREATECH), Cheonan 31253, KoreaSchool of Energy, Materials and Chemical Engineering, Korea University of Technology and Education (KOREATECH), Cheonan 31253, KoreaSchool of Energy, Materials and Chemical Engineering, Korea University of Technology and Education (KOREATECH), Cheonan 31253, KoreaSchool of Energy, Materials and Chemical Engineering, Korea University of Technology and Education (KOREATECH), Cheonan 31253, KoreaAluminum-based amorphous alloys exhibited an abnormally high vapor pressure at their approximate glass transition temperatures. The vapor pressure was confirmed by the formation of Al nanocrystallites from condensation, which was attributed to weight loss of the amorphous alloys. The amount of weight loss varied with the amorphous alloy compositions and was inversely proportional to their glass-forming ability. The vapor pressure of the amorphous alloys around 573 K was close to the vapor pressure of crystalline Al near its melting temperature, 873 K. Our results strongly suggest the possibility of fabricating nanocrystallites or thin films by evaporation at low temperatures.http://www.mdpi.com/2075-4701/5/4/1878amorphous alloymetallic glassvapor pressureglass forming ability
spellingShingle Jae Im Jeong
Sung Hyuk Lee
Je-Beom Jeon
Suk Jun Kim
Excessively High Vapor Pressure of Al-based Amorphous Alloys
Metals
amorphous alloy
metallic glass
vapor pressure
glass forming ability
title Excessively High Vapor Pressure of Al-based Amorphous Alloys
title_full Excessively High Vapor Pressure of Al-based Amorphous Alloys
title_fullStr Excessively High Vapor Pressure of Al-based Amorphous Alloys
title_full_unstemmed Excessively High Vapor Pressure of Al-based Amorphous Alloys
title_short Excessively High Vapor Pressure of Al-based Amorphous Alloys
title_sort excessively high vapor pressure of al based amorphous alloys
topic amorphous alloy
metallic glass
vapor pressure
glass forming ability
url http://www.mdpi.com/2075-4701/5/4/1878
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AT sunghyuklee excessivelyhighvaporpressureofalbasedamorphousalloys
AT jebeomjeon excessivelyhighvaporpressureofalbasedamorphousalloys
AT sukjunkim excessivelyhighvaporpressureofalbasedamorphousalloys