Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions

Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions

The allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions is described. The synergistic palladium/copper-catalyzed reaction of aromatic aldehydes, allylic carbonates, and a silylboronate produces the corresponding homoallylic alcohol derivatives. This process involves the catalytic...

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Bibliographic Details
Main Authors: Akihiro Yuasa, Kazunori Nagao, Hirohisa Ohmiya
Format: Article
Language:English
Published: Beilstein-Institut 2020-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aldehyde
copper
copper catalysis
cross-coupling
palladium
synthetic method
Online Access:https://doi.org/10.3762/bjoc.16.21

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