Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
The reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used....
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2006-11-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/11/11/929/ |
_version_ | 1811236670273486848 |
---|---|
author | Manuel Medarde Fernando Tomé Pilar Puebla Esther Caballero Javier Figueroa |
author_facet | Manuel Medarde Fernando Tomé Pilar Puebla Esther Caballero Javier Figueroa |
author_sort | Manuel Medarde |
collection | DOAJ |
description | The reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used. In addition, a systematic study of the reaction outcomes was carried out by introducing variations on the substituents of the tetrahydropyridine ring. |
first_indexed | 2024-04-12T12:13:06Z |
format | Article |
id | doaj.art-0e545434f7f243a5802f9aa9ce79e20a |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-04-12T12:13:06Z |
publishDate | 2006-11-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-0e545434f7f243a5802f9aa9ce79e20a2022-12-22T03:33:31ZengMDPI AGMolecules1420-30492006-11-01111192993910.3390/11110929Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with HydrazinesManuel MedardeFernando ToméPilar PueblaEsther CaballeroJavier FigueroaThe reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used. In addition, a systematic study of the reaction outcomes was carried out by introducing variations on the substituents of the tetrahydropyridine ring.http://www.mdpi.com/1420-3049/11/11/929/Siloxy-1236-tetrahydropyridineshydrazonespyrazolinespyridazinones. |
spellingShingle | Manuel Medarde Fernando Tomé Pilar Puebla Esther Caballero Javier Figueroa Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines Molecules Siloxy-1 2 3 6-tetrahydropyridines hydrazones pyrazolines pyridazinones. |
title | Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines |
title_full | Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines |
title_fullStr | Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines |
title_full_unstemmed | Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines |
title_short | Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines |
title_sort | reactivity of 4 tert butyldimethylsiloxy 1 2 3 6 tetrahydropyridines with hydrazines |
topic | Siloxy-1 2 3 6-tetrahydropyridines hydrazones pyrazolines pyridazinones. |
url | http://www.mdpi.com/1420-3049/11/11/929/ |
work_keys_str_mv | AT manuelmedarde reactivityof4tertbutyldimethylsiloxy1236tetrahydropyridineswithhydrazines AT fernandotomaƒa reactivityof4tertbutyldimethylsiloxy1236tetrahydropyridineswithhydrazines AT pilarpuebla reactivityof4tertbutyldimethylsiloxy1236tetrahydropyridineswithhydrazines AT esthercaballero reactivityof4tertbutyldimethylsiloxy1236tetrahydropyridineswithhydrazines AT javierfigueroa reactivityof4tertbutyldimethylsiloxy1236tetrahydropyridineswithhydrazines |