Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines

The reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used....

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Main Authors: Manuel Medarde, Fernando Tomé, Pilar Puebla, Esther Caballero, Javier Figueroa
Format: Article
Language:English
Published: MDPI AG 2006-11-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/11/11/929/
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author Manuel Medarde
Fernando Tomé
Pilar Puebla
Esther Caballero
Javier Figueroa
author_facet Manuel Medarde
Fernando Tomé
Pilar Puebla
Esther Caballero
Javier Figueroa
author_sort Manuel Medarde
collection DOAJ
description The reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used. In addition, a systematic study of the reaction outcomes was carried out by introducing variations on the substituents of the tetrahydropyridine ring.
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spelling doaj.art-0e545434f7f243a5802f9aa9ce79e20a2022-12-22T03:33:31ZengMDPI AGMolecules1420-30492006-11-01111192993910.3390/11110929Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with HydrazinesManuel MedardeFernando ToméPilar PueblaEsther CaballeroJavier FigueroaThe reactivity of 6-(nitrophenyl or trimethoxyphenyl)-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used. In addition, a systematic study of the reaction outcomes was carried out by introducing variations on the substituents of the tetrahydropyridine ring.http://www.mdpi.com/1420-3049/11/11/929/Siloxy-1236-tetrahydropyridineshydrazonespyrazolinespyridazinones.
spellingShingle Manuel Medarde
Fernando Tomé
Pilar Puebla
Esther Caballero
Javier Figueroa
Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
Molecules
Siloxy-1
2
3
6-tetrahydropyridines
hydrazones
pyrazolines
pyridazinones.
title Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
title_full Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
title_fullStr Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
title_full_unstemmed Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
title_short Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines
title_sort reactivity of 4 tert butyldimethylsiloxy 1 2 3 6 tetrahydropyridines with hydrazines
topic Siloxy-1
2
3
6-tetrahydropyridines
hydrazones
pyrazolines
pyridazinones.
url http://www.mdpi.com/1420-3049/11/11/929/
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