Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions
Codeposition of antimony and tin from acidic chloride and chloride-sulfate baths was investigated. The calculations of distribution of species showed domination of neutral SnCl2 and anionic SbCl4 – complexes in chloride solution, while in the presence of sulfate ions neutral SnSO4 and cationic SbCl2...
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| Format: | Article |
| Language: | English |
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Polish Academy of Sciences
2018-06-01
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| Series: | Archives of Metallurgy and Materials |
| Subjects: | |
| Online Access: | https://journals.pan.pl/Content/106678/PDF/AMM-2018-2-24-Rudnik.pdf |
| _version_ | 1811220320958283776 |
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| author | E. Rudnik M. Kostępski |
| author_facet | E. Rudnik M. Kostępski |
| author_sort | E. Rudnik |
| collection | DOAJ |
| description | Codeposition of antimony and tin from acidic chloride and chloride-sulfate baths was investigated. The calculations of distribution of species showed domination of neutral SnCl2 and anionic SbCl4 – complexes in chloride solution, while in the presence of sulfate ions neutral SnSO4 and cationic SbCl2+ complexes were found. Cyclic voltammetry, anodic stripping analysis and potentiostatic measurements showed that antimony deposited favorably and the reaction run under limiting control. Analysis of chronoamperometric curves suggested instantaneous nucleation of the solid phase in the chloride bath, but progressive model was more probable in the presence of sulfate ions. |
| first_indexed | 2024-04-12T07:39:41Z |
| format | Article |
| id | doaj.art-0e6944895dd047c3afec5ac3c2d80edf |
| institution | Directory Open Access Journal |
| issn | 2300-1909 |
| language | English |
| last_indexed | 2024-04-12T07:39:41Z |
| publishDate | 2018-06-01 |
| publisher | Polish Academy of Sciences |
| record_format | Article |
| series | Archives of Metallurgy and Materials |
| spelling | doaj.art-0e6944895dd047c3afec5ac3c2d80edf2022-12-22T03:41:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092018-06-01vol. 63No 2https://doi.org/10.24425/122397Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride SolutionsE. RudnikM. KostępskiCodeposition of antimony and tin from acidic chloride and chloride-sulfate baths was investigated. The calculations of distribution of species showed domination of neutral SnCl2 and anionic SbCl4 – complexes in chloride solution, while in the presence of sulfate ions neutral SnSO4 and cationic SbCl2+ complexes were found. Cyclic voltammetry, anodic stripping analysis and potentiostatic measurements showed that antimony deposited favorably and the reaction run under limiting control. Analysis of chronoamperometric curves suggested instantaneous nucleation of the solid phase in the chloride bath, but progressive model was more probable in the presence of sulfate ions.https://journals.pan.pl/Content/106678/PDF/AMM-2018-2-24-Rudnik.pdfantimonyelectrolysisspeciationtinvoltammetry |
| spellingShingle | E. Rudnik M. Kostępski Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions Archives of Metallurgy and Materials antimony electrolysis speciation tin voltammetry |
| title | Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions |
| title_full | Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions |
| title_fullStr | Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions |
| title_full_unstemmed | Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions |
| title_short | Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions |
| title_sort | comparative studies on the codeposition of antimony and tin from acidic chloride and sulfate chloride solutions |
| topic | antimony electrolysis speciation tin voltammetry |
| url | https://journals.pan.pl/Content/106678/PDF/AMM-2018-2-24-Rudnik.pdf |
| work_keys_str_mv | AT erudnik comparativestudiesonthecodepositionofantimonyandtinfromacidicchlorideandsulfatechloridesolutions AT mkostepski comparativestudiesonthecodepositionofantimonyandtinfromacidicchlorideandsulfatechloridesolutions |