Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis
Topochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved v...
| Main Authors: | , , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-11-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-021-27090-1 |
| _version_ | 1818752607702745088 |
|---|---|
| author | Christopher L. Anderson He Li Christopher G. Jones Simon J. Teat Nicholas S. Settineri Eric A. Dailing Jiatao Liang Haiyan Mao Chongqing Yang Liana M. Klivansky Xinle Li Jeffrey A. Reimer Hosea M. Nelson Yi Liu |
| author_facet | Christopher L. Anderson He Li Christopher G. Jones Simon J. Teat Nicholas S. Settineri Eric A. Dailing Jiatao Liang Haiyan Mao Chongqing Yang Liana M. Klivansky Xinle Li Jeffrey A. Reimer Hosea M. Nelson Yi Liu |
| author_sort | Christopher L. Anderson |
| collection | DOAJ |
| description | Topochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved via cryoelectron microscopy. |
| first_indexed | 2024-12-18T04:54:09Z |
| format | Article |
| id | doaj.art-0e6f6f51e3ce4ba59bfa86709d589551 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-18T04:54:09Z |
| publishDate | 2021-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-0e6f6f51e3ce4ba59bfa86709d5895512022-12-21T21:20:20ZengNature PortfolioNature Communications2041-17232021-11-011211810.1038/s41467-021-27090-1Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesisChristopher L. Anderson0He Li1Christopher G. Jones2Simon J. Teat3Nicholas S. Settineri4Eric A. Dailing5Jiatao Liang6Haiyan Mao7Chongqing Yang8Liana M. Klivansky9Xinle Li10Jeffrey A. Reimer11Hosea M. Nelson12Yi Liu13The Molecular Foundry, Lawrence Berkeley National LaboratoryThe Molecular Foundry, Lawrence Berkeley National LaboratoryDepartment of Chemistry and Biochemistry, University of California, Los AngelesAdvanced Light Source, Lawrence Berkeley National LaboratoryDepartment of Chemistry, University of California, BerkeleyThe Molecular Foundry, Lawrence Berkeley National LaboratoryThe Molecular Foundry, Lawrence Berkeley National LaboratoryDepartment of Chemical and Biomolecular Engineering, University of California, BerkeleyThe Molecular Foundry, Lawrence Berkeley National LaboratoryThe Molecular Foundry, Lawrence Berkeley National LaboratoryThe Molecular Foundry, Lawrence Berkeley National LaboratoryDepartment of Chemical and Biomolecular Engineering, University of California, BerkeleyDepartment of Chemistry and Biochemistry, University of California, Los AngelesThe Molecular Foundry, Lawrence Berkeley National LaboratoryTopochemical polymerization reactions produce ultra-high molecular weight crystalline polymers. Here the authors show a family of para-azaquinodimethane compounds that undergo facile visible light and thermally initiated polymerization in the solid state and the crystal structure has been resolved via cryoelectron microscopy.https://doi.org/10.1038/s41467-021-27090-1 |
| spellingShingle | Christopher L. Anderson He Li Christopher G. Jones Simon J. Teat Nicholas S. Settineri Eric A. Dailing Jiatao Liang Haiyan Mao Chongqing Yang Liana M. Klivansky Xinle Li Jeffrey A. Reimer Hosea M. Nelson Yi Liu Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis Nature Communications |
| title | Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis |
| title_full | Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis |
| title_fullStr | Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis |
| title_full_unstemmed | Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis |
| title_short | Solution-processable and functionalizable ultra-high molecular weight polymers via topochemical synthesis |
| title_sort | solution processable and functionalizable ultra high molecular weight polymers via topochemical synthesis |
| url | https://doi.org/10.1038/s41467-021-27090-1 |
| work_keys_str_mv | AT christopherlanderson solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT heli solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT christophergjones solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT simonjteat solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT nicholasssettineri solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT ericadailing solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT jiataoliang solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT haiyanmao solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT chongqingyang solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT lianamklivansky solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT xinleli solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT jeffreyareimer solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT hoseamnelson solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis AT yiliu solutionprocessableandfunctionalizableultrahighmolecularweightpolymersviatopochemicalsynthesis |