Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach
The synthesis of α-Fe2O3/SAPO-34 nano photocatalyst was the first step of this study. The α-Fe2O3 nanocatalyst was synthesized applying forced hydrolysis and reflux condensation followed by solid-state dispersion that was used for supporting α-Fe2O3 on SAPO-34. The next step was a characterization o...
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| Format: | Article |
| Language: | English |
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De Gruyter
2016-01-01
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| Series: | Open Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/chem-2016-0027 |
| _version_ | 1818353807528034304 |
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| author | Bigtan Mohammad Hosein Mahanpoor Kazem Shafie Hadi |
| author_facet | Bigtan Mohammad Hosein Mahanpoor Kazem Shafie Hadi |
| author_sort | Bigtan Mohammad Hosein |
| collection | DOAJ |
| description | The synthesis of α-Fe2O3/SAPO-34 nano photocatalyst was the first step of this study. The α-Fe2O3 nanocatalyst was synthesized applying forced hydrolysis and reflux condensation followed by solid-state dispersion that was used for supporting α-Fe2O3 on SAPO-34. The next step was a characterization of the catalyst that was performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FT-IR). Then, for optimizing the operational parameters in Doxorubicin’s degradation process the effect of Doxorubicin concentration, the amount of α-Fe2O3/SAPO-34 nano photocatalyst, the pH, and H2O2 concentration was studied via the Taguchi method. The AL9 orthogonal array was adjusted and nine crucial runs were conducted. For calculating Signal/Noise ratio, each run was repeated three times. As the results showed, the concentration of Doxorubicin is the most effective parameter. Optimized conditions for removing the anti-cancer drug (based on Signal/Noise ratio) were Doxorubicin concentration (20 ppm), H2O2 concentration (3 mol/L), catalyst amount (50 mg/L) and pH = 8. |
| first_indexed | 2024-12-13T19:15:24Z |
| format | Article |
| id | doaj.art-0e73135de9ef4d15b6fdafa0194eb092 |
| institution | Directory Open Access Journal |
| issn | 2391-5420 |
| language | English |
| last_indexed | 2024-12-13T19:15:24Z |
| publishDate | 2016-01-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Open Chemistry |
| spelling | doaj.art-0e73135de9ef4d15b6fdafa0194eb0922022-12-21T23:34:18ZengDe GruyterOpen Chemistry2391-54202016-01-0114126727310.1515/chem-2016-0027chem-2016-0027Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi ApproachBigtan Mohammad Hosein0Mahanpoor Kazem1Shafie Hadi2Department of Chemistry, Arak Branch, Islamic Azad University, Arak, IranDepartment of Chemistry, Arak Branch, Islamic Azad University, Arak, IranDepartment of Chemistry, Arak Branch, Islamic Azad University, Arak, IranThe synthesis of α-Fe2O3/SAPO-34 nano photocatalyst was the first step of this study. The α-Fe2O3 nanocatalyst was synthesized applying forced hydrolysis and reflux condensation followed by solid-state dispersion that was used for supporting α-Fe2O3 on SAPO-34. The next step was a characterization of the catalyst that was performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FT-IR). Then, for optimizing the operational parameters in Doxorubicin’s degradation process the effect of Doxorubicin concentration, the amount of α-Fe2O3/SAPO-34 nano photocatalyst, the pH, and H2O2 concentration was studied via the Taguchi method. The AL9 orthogonal array was adjusted and nine crucial runs were conducted. For calculating Signal/Noise ratio, each run was repeated three times. As the results showed, the concentration of Doxorubicin is the most effective parameter. Optimized conditions for removing the anti-cancer drug (based on Signal/Noise ratio) were Doxorubicin concentration (20 ppm), H2O2 concentration (3 mol/L), catalyst amount (50 mg/L) and pH = 8.https://doi.org/10.1515/chem-2016-0027doxorubicinphotocatalytic degradationα-fe2o3/sapo-34design of experimenttaguchi method |
| spellingShingle | Bigtan Mohammad Hosein Mahanpoor Kazem Shafie Hadi Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach Open Chemistry doxorubicin photocatalytic degradation α-fe2o3/sapo-34 design of experiment taguchi method |
| title | Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach |
| title_full | Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach |
| title_fullStr | Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach |
| title_full_unstemmed | Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach |
| title_short | Preparation and Application of a Nano α-Fe2O3/SAPO-34 Photocatalyst for Removal of the Anti-cancer Drug Doxorubicin using the Taguchi Approach |
| title_sort | preparation and application of a nano α fe2o3 sapo 34 photocatalyst for removal of the anti cancer drug doxorubicin using the taguchi approach |
| topic | doxorubicin photocatalytic degradation α-fe2o3/sapo-34 design of experiment taguchi method |
| url | https://doi.org/10.1515/chem-2016-0027 |
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