Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide

A cycloolefin copolymer matrix was melt mixed with exfoliated graphite nanoplatelets (xGnP) and the resulting nanocomposites were foamed by supercritical carbon dioxide. The density of the obtained foams decreased with the foaming pressure. Moreover, xGnP limited the cell growth during the expansion...

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Main Authors: A. Biani, A. Dorigato, W. Bonani, M. Slouf, A. Pegoretti
Format: Article
Language:English
Published: Budapest University of Technology 2016-12-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0007313&mi=cd
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author A. Biani
A. Dorigato
W. Bonani
M. Slouf
A. Pegoretti
author_facet A. Biani
A. Dorigato
W. Bonani
M. Slouf
A. Pegoretti
author_sort A. Biani
collection DOAJ
description A cycloolefin copolymer matrix was melt mixed with exfoliated graphite nanoplatelets (xGnP) and the resulting nanocomposites were foamed by supercritical carbon dioxide. The density of the obtained foams decreased with the foaming pressure. Moreover, xGnP limited the cell growth during the expansion process thus reducing the cell diameter (from 1.08 to 0.22 mm with an XGnP amount of 10 wt% at 150 bar) and increasing the cell density (from 12 to 45 cells/mm2 with a nanofiller content of 10 wt% at 150 bar). Electron microscopy observations of foams evidenced exfoliation and orientation of the nanoplatelets along the cell walls. Quasi-static compressive tests and tensile creep tests on foams clearly indicated that xGnP improved the modulus (up to a factor of 10 for a xGnP content of 10 wt%) and the creep stability.
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spelling doaj.art-0ea35081fbe24a14acc139d3275213e72022-12-21T18:29:41ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2016-12-01101297798910.3144/expresspolymlett.2016.91Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxideA. BianiA. DorigatoW. BonaniM. SloufA. PegorettiA cycloolefin copolymer matrix was melt mixed with exfoliated graphite nanoplatelets (xGnP) and the resulting nanocomposites were foamed by supercritical carbon dioxide. The density of the obtained foams decreased with the foaming pressure. Moreover, xGnP limited the cell growth during the expansion process thus reducing the cell diameter (from 1.08 to 0.22 mm with an XGnP amount of 10 wt% at 150 bar) and increasing the cell density (from 12 to 45 cells/mm2 with a nanofiller content of 10 wt% at 150 bar). Electron microscopy observations of foams evidenced exfoliation and orientation of the nanoplatelets along the cell walls. Quasi-static compressive tests and tensile creep tests on foams clearly indicated that xGnP improved the modulus (up to a factor of 10 for a xGnP content of 10 wt%) and the creep stability.http://www.expresspolymlett.com/letolt.php?file=EPL-0007313&mi=cdNanocompositesFoamsGraphene nanoplatelets
spellingShingle A. Biani
A. Dorigato
W. Bonani
M. Slouf
A. Pegoretti
Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
eXPRESS Polymer Letters
Nanocomposites
Foams
Graphene nanoplatelets
title Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
title_full Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
title_fullStr Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
title_full_unstemmed Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
title_short Mechanical behaviour of cyclic olefin copolymer/exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
title_sort mechanical behaviour of cyclic olefin copolymer exfoliated graphite nanoplatelets nanocomposites foamed through supercritical carbon dioxide
topic Nanocomposites
Foams
Graphene nanoplatelets
url http://www.expresspolymlett.com/letolt.php?file=EPL-0007313&mi=cd
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