| Summary: | As a continuation of research on 1-vinylazulenes synthesis, on their physico–chemical properties as well as on their use as colorimetric and electrochemical materials for the detection of heavy metals ions, new compounds, 4-(azulen-1-ylmethylene)-2-phenyloxazol-5(4H)-ones, are reported. The exceptional structure of azulene moiety with symmetrical electron distribution only with respect to the <i>x</i>-axis gives some special chemical and physical properties to compounds in which it is inserted. Various azulene-1-carbaldehydes and hippuric acids are condensed with good yields in Erlenmeyer—Plöchl reaction conditions. The obtained 1-vinylzulenes were characterized and their UV-Vis and NMR spectra were briefly discussed.
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