[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III)
The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom me...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811001395 |
| _version_ | 1819280137588310016 |
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| author | Nan Xu Douglas R. Powell George B. Richter-Addo |
| author_facet | Nan Xu Douglas R. Powell George B. Richter-Addo |
| author_sort | Nan Xu |
| collection | DOAJ |
| description | The title compound, [Fe(CF3O3S)(C48H36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—Np distance is 2.044 (2) Å and the Fe—O distance is 2.001 (2) Å. |
| first_indexed | 2024-12-24T00:39:01Z |
| format | Article |
| id | doaj.art-0f0c39ce76f0487180dc717044eb3e02 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:01Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0f0c39ce76f0487180dc717044eb3e022022-12-21T17:24:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m268m26810.1107/S1600536811001395[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III)Nan XuDouglas R. PowellGeorge B. Richter-AddoThe title compound, [Fe(CF3O3S)(C48H36N4O4)], is a five-coordinate iron(III) porphyrin complex with a trifluoromethanesulfonate anion as an axial ligand. The FeIII atom is displaced by 0.40 (1) Å towards the trifluoromethanesulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—Np distance is 2.044 (2) Å and the Fe—O distance is 2.001 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536811001395 |
| spellingShingle | Nan Xu Douglas R. Powell George B. Richter-Addo [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) Acta Crystallographica Section E |
| title | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) |
| title_full | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) |
| title_fullStr | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) |
| title_full_unstemmed | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) |
| title_short | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato-κ4N,N′,N′′,N′′′](trifluoromethanesulfonato-κO)iron(III) |
| title_sort | 5 10 15 20 tetrakis 4 methoxyphenyl porphyrinato amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 trifluoromethanesulfonato amp 954 o iron iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811001395 |
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