N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

A technique has been proposed for incorporating a heterocyclic component into a glutarimide framework employing a Rh2(esp)2-catalyzed N–H insertion with the involvement of N-Boc-α-diazo glutarimide. The new diazo reagent is more stable, soluble and convenient to prepare than the previously suggested...

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Bibliographic Details
Main Authors: Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev, Dmitry Dar’in
Format: Article
Language:English
Published: Beilstein-Institut 2023-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
crbn ligands
diazocarbonyl compounds
n–h insertion reaction
n-heterocycles
rh(ii)-catalysis
Online Access:https://doi.org/10.3762/bjoc.19.136

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