Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)

Summary: The distribution of metals (Pb, Cu, Cd, Ni, Cr, Zn) in surface sediments and the potential pollution sources in the south-eastern part (SE) of the Baltic Sea (Lithuanian zone) were investigated in relation to the environmental characteristics (amount of fine-grained particles, TOC content i...

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Main Authors: Nijolė Remeikaitė-Nikienė, Galina Garnaga-Budrė, Galina Lujanienė, Kęstutis Jokšas, Algirdas Stankevičius, Vitalijus Malejevas, Rūta Barisevičiūtė
Format: Article
Language:English
Published: Elsevier 2018-04-01
Series:Oceanologia
Online Access:http://www.sciencedirect.com/science/article/pii/S007832341730101X
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author Nijolė Remeikaitė-Nikienė
Galina Garnaga-Budrė
Galina Lujanienė
Kęstutis Jokšas
Algirdas Stankevičius
Vitalijus Malejevas
Rūta Barisevičiūtė
author_facet Nijolė Remeikaitė-Nikienė
Galina Garnaga-Budrė
Galina Lujanienė
Kęstutis Jokšas
Algirdas Stankevičius
Vitalijus Malejevas
Rūta Barisevičiūtė
author_sort Nijolė Remeikaitė-Nikienė
collection DOAJ
description Summary: The distribution of metals (Pb, Cu, Cd, Ni, Cr, Zn) in surface sediments and the potential pollution sources in the south-eastern part (SE) of the Baltic Sea (Lithuanian zone) were investigated in relation to the environmental characteristics (amount of fine-grained particles, TOC content in sediments, origin of sedimentary organic matter, salinity, water depth) in 2011–2014. The higher metal concentrations were measured in sediments of the Curonian Lagoon and in the open waters. An approach using various environmental indices (enrichment factor EF, geoaccumulation index Igeo and contamination factor CF) was used to quantitatively assess a contamination degree. The principal component analysis (PCA) was applied in order to further scrutinize pollution from metal sources. The values of the contamination indices showed no/very low sediment contamination with Ni and Cr, minor–moderate contamination with Cu, Zn and Pb and moderate–considerable pollution with Cd. The strong relationships among metals suggested their similar distribution pattern and a combination of natural and anthropogenic sources. The higher metal concentrations coincided with an increasing amount of fine-grained fraction and organic carbon. In the territorial waters, the distribution of elements was related to the water depth. In addition, the binding of metals with insoluble iron sulphides might explain their high concentrations at the most remote and deepest stations. Keywords: Metals, Enrichment factor, Geoaccumulation index, Contamination factor, The Baltic Sea, The Curonian Lagoon
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spelling doaj.art-0f2f7873da3a44c8ac3e9c4891fa65012022-12-22T03:20:06ZengElsevierOceanologia0078-32342018-04-01602193206Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)Nijolė Remeikaitė-Nikienė0Galina Garnaga-Budrė1Galina Lujanienė2Kęstutis Jokšas3Algirdas Stankevičius4Vitalijus Malejevas5Rūta Barisevičiūtė6Environmental Protection Agency, Department of Marine Research, Klaipėda, Lithuania; State Research Institute Center for Physical Sciences and Technology, Vilnius, Lithuania; Corresponding author. Environmental Protection Agency, Department of Marine Research, Taikos av. 26, LT-91222, Klaipėda, Lithuania. Tel.: +370 46 41 0450; fax. +370 46 41 0460.Environmental Protection Agency, Department of Marine Research, Klaipėda, Lithuania; Klaipėda University, Klaipėda, LithuaniaState Research Institute Center for Physical Sciences and Technology, Vilnius, LithuaniaNature Research Center, Institute of Geology and Geography, Vilnius, Lithuania; Vilnius University, Vilnius, LithuaniaEnvironmental Protection Agency, Department of Marine Research, Klaipėda, Lithuania; Klaipėda University, Klaipėda, LithuaniaEnvironmental Protection Agency, Department of Marine Research, Klaipėda, Lithuania; State Research Institute Center for Physical Sciences and Technology, Vilnius, LithuaniaState Research Institute Center for Physical Sciences and Technology, Vilnius, LithuaniaSummary: The distribution of metals (Pb, Cu, Cd, Ni, Cr, Zn) in surface sediments and the potential pollution sources in the south-eastern part (SE) of the Baltic Sea (Lithuanian zone) were investigated in relation to the environmental characteristics (amount of fine-grained particles, TOC content in sediments, origin of sedimentary organic matter, salinity, water depth) in 2011–2014. The higher metal concentrations were measured in sediments of the Curonian Lagoon and in the open waters. An approach using various environmental indices (enrichment factor EF, geoaccumulation index Igeo and contamination factor CF) was used to quantitatively assess a contamination degree. The principal component analysis (PCA) was applied in order to further scrutinize pollution from metal sources. The values of the contamination indices showed no/very low sediment contamination with Ni and Cr, minor–moderate contamination with Cu, Zn and Pb and moderate–considerable pollution with Cd. The strong relationships among metals suggested their similar distribution pattern and a combination of natural and anthropogenic sources. The higher metal concentrations coincided with an increasing amount of fine-grained fraction and organic carbon. In the territorial waters, the distribution of elements was related to the water depth. In addition, the binding of metals with insoluble iron sulphides might explain their high concentrations at the most remote and deepest stations. Keywords: Metals, Enrichment factor, Geoaccumulation index, Contamination factor, The Baltic Sea, The Curonian Lagoonhttp://www.sciencedirect.com/science/article/pii/S007832341730101X
spellingShingle Nijolė Remeikaitė-Nikienė
Galina Garnaga-Budrė
Galina Lujanienė
Kęstutis Jokšas
Algirdas Stankevičius
Vitalijus Malejevas
Rūta Barisevičiūtė
Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
Oceanologia
title Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
title_full Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
title_fullStr Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
title_full_unstemmed Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
title_short Distribution of metals and extent of contamination in sediments from the south-eastern Baltic Sea (Lithuanian zone)
title_sort distribution of metals and extent of contamination in sediments from the south eastern baltic sea lithuanian zone
url http://www.sciencedirect.com/science/article/pii/S007832341730101X
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