μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate
The asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent TeIV cations, each coordinated by three phenyl ligands, two Cl− anions and one acetic acid molecule in a distorted octahedral C3Cl2O geometry; the longer Te...Cl distances ranging from 3.2007&a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681301739X |
| _version_ | 1798018576058155008 |
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| author | Feng Hu Chao Xu Hua-Tian Shi Qun Chen Qian-Feng Zhang |
| author_facet | Feng Hu Chao Xu Hua-Tian Shi Qun Chen Qian-Feng Zhang |
| author_sort | Feng Hu |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent TeIV cations, each coordinated by three phenyl ligands, two Cl− anions and one acetic acid molecule in a distorted octahedral C3Cl2O geometry; the longer Te...Cl distances ranging from 3.2007 (11) to 3.4407 (11) Å and the longer Te...O distances of 3.067 (3) and 3.113 (3) Å indicate the weak bridge coordination. The Cl− anion and acetic acid molecule bridge the two independent TeIV cations, forming the dimeric complex molecule, in which the Te...Te separation is 3.7314 (4) Å. In the crystal, the water molecules of crystallization link the TeIV complex molecules into chains running along the b-axis direction via O—H...O and O—H...Cl hydrogen bonds. |
| first_indexed | 2024-04-11T16:26:24Z |
| format | Article |
| id | doaj.art-0f52559413f246948b8f3b2dbfd74f1e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:26:24Z |
| publishDate | 2013-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0f52559413f246948b8f3b2dbfd74f1e2022-12-22T04:14:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697o1171o117110.1107/S160053681301739Xμ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrateFeng HuChao XuHua-Tian ShiQun ChenQian-Feng ZhangThe asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent TeIV cations, each coordinated by three phenyl ligands, two Cl− anions and one acetic acid molecule in a distorted octahedral C3Cl2O geometry; the longer Te...Cl distances ranging from 3.2007 (11) to 3.4407 (11) Å and the longer Te...O distances of 3.067 (3) and 3.113 (3) Å indicate the weak bridge coordination. The Cl− anion and acetic acid molecule bridge the two independent TeIV cations, forming the dimeric complex molecule, in which the Te...Te separation is 3.7314 (4) Å. In the crystal, the water molecules of crystallization link the TeIV complex molecules into chains running along the b-axis direction via O—H...O and O—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S160053681301739X |
| spellingShingle | Feng Hu Chao Xu Hua-Tian Shi Qun Chen Qian-Feng Zhang μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate Acta Crystallographica Section E |
| title | μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate |
| title_full | μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate |
| title_fullStr | μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate |
| title_full_unstemmed | μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate |
| title_short | μ-(Acetic acid)-di-μ-chlorido-bis[triphenyltellurium(IV)] monohydrate |
| title_sort | 956 acetic acid di 956 chlorido bis triphenyltellurium iv monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681301739X |
| work_keys_str_mv | AT fenghu 956aceticaciddi956chloridobistriphenyltelluriumivmonohydrate AT chaoxu 956aceticaciddi956chloridobistriphenyltelluriumivmonohydrate AT huatianshi 956aceticaciddi956chloridobistriphenyltelluriumivmonohydrate AT qunchen 956aceticaciddi956chloridobistriphenyltelluriumivmonohydrate AT qianfengzhang 956aceticaciddi956chloridobistriphenyltelluriumivmonohydrate |