A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene
Over the past few years, conjugated polymers (CPs) have aroused much attention owing to their rigid conjugated structures, which can perform well in light harvesting and energy transfer and offer great potential in materials chemistry. In this article, we fabricate a new luminescent linear CP p(P[5]...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-05-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/10/3162 |
| _version_ | 1797497480769699840 |
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| author | Dinghui Wang Jun Wang Yan Wang Yingwei Yang |
| author_facet | Dinghui Wang Jun Wang Yan Wang Yingwei Yang |
| author_sort | Dinghui Wang |
| collection | DOAJ |
| description | Over the past few years, conjugated polymers (CPs) have aroused much attention owing to their rigid conjugated structures, which can perform well in light harvesting and energy transfer and offer great potential in materials chemistry. In this article, we fabricate a new luminescent linear CP p(P[5](OTf)<sub>2</sub>-<i>co</i>-9,10-dea) via the Sonogashira coupling of 9,10-diethynylanthracene and trifluoromethanesulfonic anhydride (OTf) modified pillar[5]arene, generating enhanced yellow-green fluorescence emission at around 552 nm. The reaction condition was screened to get a deeper understanding of this polymerization approach, resulting in an excellent yield as high as 92% ultimately. Besides the optical properties, self-assembly behaviors of the CP in low/high concentrations were studied, where interesting adjustable morphologies from tube to sheet were observed. In addition, the fluorescence performance and structural architecture can be disturbed by the host–guest reorganization between the host CP and the guest adiponitrile, suggesting great potential of this CP material in the field of sensing and detection. |
| first_indexed | 2024-03-10T03:19:49Z |
| format | Article |
| id | doaj.art-0f64d038692c45f780db557d093e5f82 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T03:19:49Z |
| publishDate | 2022-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-0f64d038692c45f780db557d093e5f822023-11-23T12:22:02ZengMDPI AGMolecules1420-30492022-05-012710316210.3390/molecules27103162A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and AnthraceneDinghui Wang0Jun Wang1Yan Wang2Yingwei Yang3International Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, ChinaInternational Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, ChinaInternational Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, ChinaInternational Joint Research Laboratory of Nano-Micro Architecture Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, ChinaOver the past few years, conjugated polymers (CPs) have aroused much attention owing to their rigid conjugated structures, which can perform well in light harvesting and energy transfer and offer great potential in materials chemistry. In this article, we fabricate a new luminescent linear CP p(P[5](OTf)<sub>2</sub>-<i>co</i>-9,10-dea) via the Sonogashira coupling of 9,10-diethynylanthracene and trifluoromethanesulfonic anhydride (OTf) modified pillar[5]arene, generating enhanced yellow-green fluorescence emission at around 552 nm. The reaction condition was screened to get a deeper understanding of this polymerization approach, resulting in an excellent yield as high as 92% ultimately. Besides the optical properties, self-assembly behaviors of the CP in low/high concentrations were studied, where interesting adjustable morphologies from tube to sheet were observed. In addition, the fluorescence performance and structural architecture can be disturbed by the host–guest reorganization between the host CP and the guest adiponitrile, suggesting great potential of this CP material in the field of sensing and detection.https://www.mdpi.com/1420-3049/27/10/3162conjugated polymerhost–guest interactionpillararenesupramolecular chemistrylight-emitting materials |
| spellingShingle | Dinghui Wang Jun Wang Yan Wang Yingwei Yang A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene Molecules conjugated polymer host–guest interaction pillararene supramolecular chemistry light-emitting materials |
| title | A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene |
| title_full | A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene |
| title_fullStr | A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene |
| title_full_unstemmed | A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene |
| title_short | A Fluorescent Linear Conjugated Polymer Constructed from Pillararene and Anthracene |
| title_sort | fluorescent linear conjugated polymer constructed from pillararene and anthracene |
| topic | conjugated polymer host–guest interaction pillararene supramolecular chemistry light-emitting materials |
| url | https://www.mdpi.com/1420-3049/27/10/3162 |
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