Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines
The development of poly (vinyl alcohol)/Hibiscus sabdariffa extract modified silicate-coated Fe3O4 nanoparticles (Fe3O4@SiO2-Hs/PVA) presents an economical and environmental-friendly heterogeneous catalytic system for amines oxidation with hydrogen peroxide. The prepared nanocatalyst was determined...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-01-01
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| Series: | Results in Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715622002028 |
| _version_ | 1798006361284411392 |
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| author | Pegah Haghighi Hakimeh Ziyadi Malak Hekmati Navid Habibnejad Sheyda Iranfar |
| author_facet | Pegah Haghighi Hakimeh Ziyadi Malak Hekmati Navid Habibnejad Sheyda Iranfar |
| author_sort | Pegah Haghighi |
| collection | DOAJ |
| description | The development of poly (vinyl alcohol)/Hibiscus sabdariffa extract modified silicate-coated Fe3O4 nanoparticles (Fe3O4@SiO2-Hs/PVA) presents an economical and environmental-friendly heterogeneous catalytic system for amines oxidation with hydrogen peroxide. The prepared nanocatalyst was determined using FT-IR, SEM, TEM, and XRD analyses and was used as a magnetic catalyst in the amine oxidation reaction. A large group of N-oxides has been obtained in good – high yields under optimal reaction conditions. The prepared nanocatalyst was recovered through an external magnetic field and was reused successfully for five cycles without any obvious loss in catalytic performance. The major beneficial characteristics of the present approach are a simple preparation pathway, less usage of hazardous reagents, broad substrate scope, and magnetically recoverable nanocatalyst. |
| first_indexed | 2024-04-11T12:53:33Z |
| format | Article |
| id | doaj.art-0f7cdc648b1f4469819a2ac0841e74ff |
| institution | Directory Open Access Journal |
| issn | 2211-7156 |
| language | English |
| last_indexed | 2024-04-11T12:53:33Z |
| publishDate | 2022-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Results in Chemistry |
| spelling | doaj.art-0f7cdc648b1f4469819a2ac0841e74ff2022-12-22T04:23:08ZengElsevierResults in Chemistry2211-71562022-01-014100483Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of aminesPegah Haghighi0Hakimeh Ziyadi1Malak Hekmati2Navid Habibnejad3Sheyda Iranfar4Active Pharmaceutical Ingredients Research Center, Tehran Medical Sciences, Islamic Azad University, Tehran, IranDepartment of Organic Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran; Corresponding author.Department of Organic Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, Tehran, IranChemistry & Chemical Engineering Research Center of Iran (CCERCI), P.O. Box 14335-186, Tehran, IranActive Pharmaceutical Ingredients Research Center, Tehran Medical Sciences, Islamic Azad University, Tehran, IranThe development of poly (vinyl alcohol)/Hibiscus sabdariffa extract modified silicate-coated Fe3O4 nanoparticles (Fe3O4@SiO2-Hs/PVA) presents an economical and environmental-friendly heterogeneous catalytic system for amines oxidation with hydrogen peroxide. The prepared nanocatalyst was determined using FT-IR, SEM, TEM, and XRD analyses and was used as a magnetic catalyst in the amine oxidation reaction. A large group of N-oxides has been obtained in good – high yields under optimal reaction conditions. The prepared nanocatalyst was recovered through an external magnetic field and was reused successfully for five cycles without any obvious loss in catalytic performance. The major beneficial characteristics of the present approach are a simple preparation pathway, less usage of hazardous reagents, broad substrate scope, and magnetically recoverable nanocatalyst.http://www.sciencedirect.com/science/article/pii/S2211715622002028Magnetic nanocatalystHibiscus sabdariffaPVAOxidationAmines |
| spellingShingle | Pegah Haghighi Hakimeh Ziyadi Malak Hekmati Navid Habibnejad Sheyda Iranfar Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines Results in Chemistry Magnetic nanocatalyst Hibiscus sabdariffa PVA Oxidation Amines |
| title | Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| title_full | Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| title_fullStr | Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| title_full_unstemmed | Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| title_short | Hibiscus sabdariffa extract/poly (vinyl alcohol) modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| title_sort | hibiscus sabdariffa extract poly vinyl alcohol modified magnetite as a magnetically recyclable nanocatalyst for the selective oxidation of amines |
| topic | Magnetic nanocatalyst Hibiscus sabdariffa PVA Oxidation Amines |
| url | http://www.sciencedirect.com/science/article/pii/S2211715622002028 |
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