Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface
This paper presents a new type of black organic material-porous silica composite providing an extremely highly selective adsorption surface. This black composite was prepared by lamination on nano-sized pores with a carbon-like, π-extended structure, which can be converted via the on-site polymeriza...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-09-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/10/9/1882 |
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| author | Hiroki Noguchi Marzia Sultana Nanami Hano Yutaka Kuwahara Makoto Takafuji Shoji Nagaoka Hongdeng Qiu Hirotaka Ihara |
| author_facet | Hiroki Noguchi Marzia Sultana Nanami Hano Yutaka Kuwahara Makoto Takafuji Shoji Nagaoka Hongdeng Qiu Hirotaka Ihara |
| author_sort | Hiroki Noguchi |
| collection | DOAJ |
| description | This paper presents a new type of black organic material-porous silica composite providing an extremely highly selective adsorption surface. This black composite was prepared by lamination on nano-sized pores with a carbon-like, π-extended structure, which can be converted via the on-site polymerization of 1,5-dihydroxynaphthalene with a triazinane derivative and a thermally induced condensation reaction with denitrification. This bottom-up fabrication method on porous materials had the great advantage of maintaining the pore characteristics of a raw porous material, but also the resultant black surface exhibited an extremely high molecular-shape selectivity; for example, that for <i>trans</i>- and <i>cis-</i>stilbenes reached 14.0 with the black layer-laminated porous silica, whereas it was below 1.2 with simple hydrophobized silica. |
| first_indexed | 2024-03-10T16:11:17Z |
| format | Article |
| id | doaj.art-0f7f99cf1d0e4e4aa09b49b37cce5aad |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-10T16:11:17Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-0f7f99cf1d0e4e4aa09b49b37cce5aad2023-11-20T14:24:43ZengMDPI AGNanomaterials2079-49912020-09-01109188210.3390/nano10091882Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica SurfaceHiroki Noguchi0Marzia Sultana1Nanami Hano2Yutaka Kuwahara3Makoto Takafuji4Shoji Nagaoka5Hongdeng Qiu6Hirotaka Ihara7Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanLanzhou Institute of Chemical Physics, Chinese Academy of Science, 18, Tianshui Middle Road, Lanzhou 730000, ChinaDepartment of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, JapanThis paper presents a new type of black organic material-porous silica composite providing an extremely highly selective adsorption surface. This black composite was prepared by lamination on nano-sized pores with a carbon-like, π-extended structure, which can be converted via the on-site polymerization of 1,5-dihydroxynaphthalene with a triazinane derivative and a thermally induced condensation reaction with denitrification. This bottom-up fabrication method on porous materials had the great advantage of maintaining the pore characteristics of a raw porous material, but also the resultant black surface exhibited an extremely high molecular-shape selectivity; for example, that for <i>trans</i>- and <i>cis-</i>stilbenes reached 14.0 with the black layer-laminated porous silica, whereas it was below 1.2 with simple hydrophobized silica.https://www.mdpi.com/2079-4991/10/9/1882amorphous carbonblack materialsorganic-inorganic hybrid materialsπ–π interactionadsorbentgeometrical selectivity |
| spellingShingle | Hiroki Noguchi Marzia Sultana Nanami Hano Yutaka Kuwahara Makoto Takafuji Shoji Nagaoka Hongdeng Qiu Hirotaka Ihara Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface Nanomaterials amorphous carbon black materials organic-inorganic hybrid materials π–π interaction adsorbent geometrical selectivity |
| title | Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface |
| title_full | Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface |
| title_fullStr | Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface |
| title_full_unstemmed | Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface |
| title_short | Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface |
| title_sort | fabrication of carbon like π conjugated organic layer on a nano porous silica surface |
| topic | amorphous carbon black materials organic-inorganic hybrid materials π–π interaction adsorbent geometrical selectivity |
| url | https://www.mdpi.com/2079-4991/10/9/1882 |
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