Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study

Biofouling is one of the drawbacks restricting the industrial applications of membranes. In this study, different thicknesses of silver nanoparticles with proper adhesion were deposited on poly(vinylidenefluoride) (PVDF) and polyethersulfone (PES) surfaces by physical vapor deposition (PVD). The cry...

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Main Authors: Maryam Amouamouha, Gagik Badalians Gholikandi
Format: Article
Language:English
Published: MDPI AG 2017-11-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/7/4/64
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author Maryam Amouamouha
Gagik Badalians Gholikandi
author_facet Maryam Amouamouha
Gagik Badalians Gholikandi
author_sort Maryam Amouamouha
collection DOAJ
description Biofouling is one of the drawbacks restricting the industrial applications of membranes. In this study, different thicknesses of silver nanoparticles with proper adhesion were deposited on poly(vinylidenefluoride) (PVDF) and polyethersulfone (PES) surfaces by physical vapor deposition (PVD). The crystalline and structural properties of modified and pure membranes were investigated by carrying out X-ray diffraction (XRD) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR). Scanning electron microscope (SEM) and atomic force microscopy (AFM) analyses were employed to examine the surface morphology and the bacteria anti-adhesion property of the membranes. The morphology measurements confirmed that even though after silver grafting the surface became more hydrophobic, the homogeneity increased and the flux reduction decreased after coating. Moreover a comparison between PVDF and PES revealed that CFU (colony forming units) reduced 64.5% on PVDF surface and 31.1% on PES surface after modification. In conclusion, PVD improved the performance of the membrane antibiofouling, and it is more promising to be used for PVDF rather than PES.
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spelling doaj.art-0f9597ab858341c08a0c4b2ffb832a192023-08-02T09:09:25ZengMDPI AGMembranes2077-03752017-11-01746410.3390/membranes7040064membranes7040064Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative StudyMaryam Amouamouha0Gagik Badalians Gholikandi1Faculty of Civil, Water and Environmental Engineering, A.C., Shahid Beheshti University, Tehran 1658953571, IranFaculty of Civil, Water and Environmental Engineering, A.C., Shahid Beheshti University, Tehran 1658953571, IranBiofouling is one of the drawbacks restricting the industrial applications of membranes. In this study, different thicknesses of silver nanoparticles with proper adhesion were deposited on poly(vinylidenefluoride) (PVDF) and polyethersulfone (PES) surfaces by physical vapor deposition (PVD). The crystalline and structural properties of modified and pure membranes were investigated by carrying out X-ray diffraction (XRD) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR). Scanning electron microscope (SEM) and atomic force microscopy (AFM) analyses were employed to examine the surface morphology and the bacteria anti-adhesion property of the membranes. The morphology measurements confirmed that even though after silver grafting the surface became more hydrophobic, the homogeneity increased and the flux reduction decreased after coating. Moreover a comparison between PVDF and PES revealed that CFU (colony forming units) reduced 64.5% on PVDF surface and 31.1% on PES surface after modification. In conclusion, PVD improved the performance of the membrane antibiofouling, and it is more promising to be used for PVDF rather than PES.https://www.mdpi.com/2077-0375/7/4/64antibiofoulingpoly(vinylidenefluoride) (PVDF)polyethersulfone (PES)silver nanoparticleshydrophobicity
spellingShingle Maryam Amouamouha
Gagik Badalians Gholikandi
Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
Membranes
antibiofouling
poly(vinylidenefluoride) (PVDF)
polyethersulfone (PES)
silver nanoparticles
hydrophobicity
title Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
title_full Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
title_fullStr Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
title_full_unstemmed Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
title_short Characterization and Antibiofouling Performance Investigation of Hydrophobic Silver Nanocomposite Membranes: A Comparative Study
title_sort characterization and antibiofouling performance investigation of hydrophobic silver nanocomposite membranes a comparative study
topic antibiofouling
poly(vinylidenefluoride) (PVDF)
polyethersulfone (PES)
silver nanoparticles
hydrophobicity
url https://www.mdpi.com/2077-0375/7/4/64
work_keys_str_mv AT maryamamouamouha characterizationandantibiofoulingperformanceinvestigationofhydrophobicsilvernanocompositemembranesacomparativestudy
AT gagikbadaliansgholikandi characterizationandantibiofoulingperformanceinvestigationofhydrophobicsilvernanocompositemembranesacomparativestudy