3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation
The asymmetric unit of title hydrated salt, C22H46N42+·2Cl−·4H2O, comprises half a centrosymmetric dication, one Cl− anion and two water molecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813027232 |
| _version_ | 1818960261413863424 |
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| author | Dohyun Moon Md Abdus Subhan Jong-Ha Choi |
| author_facet | Dohyun Moon Md Abdus Subhan Jong-Ha Choi |
| author_sort | Dohyun Moon |
| collection | DOAJ |
| description | The asymmetric unit of title hydrated salt, C22H46N42+·2Cl−·4H2O, comprises half a centrosymmetric dication, one Cl− anion and two water molecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine N atoms, and that the dication features intramolecular N—H...N hydrogen bonds. In the crystal, a three-dimensional artchitecture is formed by O—H...Cl/N and N—H...Cl/O hydrogen bonds. |
| first_indexed | 2024-12-20T11:54:43Z |
| format | Article |
| id | doaj.art-0faa7f3c12854f3787f9d2994ce2cd45 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:54:43Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0faa7f3c12854f3787f9d2994ce2cd452022-12-21T19:41:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911o1620o162010.1107/S16005368130272323,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiationDohyun MoonMd Abdus SubhanJong-Ha ChoiThe asymmetric unit of title hydrated salt, C22H46N42+·2Cl−·4H2O, comprises half a centrosymmetric dication, one Cl− anion and two water molecules of crystallization. The structure determination reveals that protonation has occurred at diagonally opposite amine N atoms, and that the dication features intramolecular N—H...N hydrogen bonds. In the crystal, a three-dimensional artchitecture is formed by O—H...Cl/N and N—H...Cl/O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536813027232 |
| spellingShingle | Dohyun Moon Md Abdus Subhan Jong-Ha Choi 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation Acta Crystallographica Section E |
| title | 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation |
| title_full | 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation |
| title_fullStr | 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation |
| title_full_unstemmed | 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation |
| title_short | 3,14-Diethyl-2,13-diaza-6,17-diazoniatricyclo[16.4.0.07,12]docosane dichloride tetrahydrate from synchrotron radiation |
| title_sort | 3 14 diethyl 2 13 diaza 6 17 diazoniatricyclo 16 4 0 07 12 docosane dichloride tetrahydrate from synchrotron radiation |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813027232 |
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