In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks
We report a series of Pd K-edge and Pt L3-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at differen...
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| Format: | Article |
| Language: | English |
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Elsevier
2019-08-01
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| Series: | Data in Brief |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2352340919306341 |
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| author | Aram L. Bugaev Alina A. Skorynina Elizaveta G. Kamyshova Kirill A. Lomachenko Alexander A. Guda Alexander V. Soldatov Carlo Lamberti |
| author_facet | Aram L. Bugaev Alina A. Skorynina Elizaveta G. Kamyshova Kirill A. Lomachenko Alexander A. Guda Alexander V. Soldatov Carlo Lamberti |
| author_sort | Aram L. Bugaev |
| collection | DOAJ |
| description | We report a series of Pd K-edge and Pt L3-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at different beamlines, normalized XAS spectra and k2-weighted oscillatory χ(k) functions extracted from one of the datasets. Pd K-edge spectra were collected for the samples in 5% H2/He, 3% H2/He and pure He in the temperature range from room temperature (RT) to 450 °C. Pt L3-edge were collected for the samples in 3% H2/He, 10% H2/He and pure He in the temperature range from RT to 300 °C. All spectra are reported together with the used atmosphere and temperature. For the analysis of all reported datasets, please see “Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks”. Fourier-analysis of Pd K-edge is reported in “Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS”. Keywords: EXAFS, XANES, MOFs, Nanoparticles |
| first_indexed | 2024-04-12T02:22:57Z |
| format | Article |
| id | doaj.art-0fb017d4b9224a7aa9a74d44f80d20da |
| institution | Directory Open Access Journal |
| issn | 2352-3409 |
| language | English |
| last_indexed | 2024-04-12T02:22:57Z |
| publishDate | 2019-08-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Data in Brief |
| spelling | doaj.art-0fb017d4b9224a7aa9a74d44f80d20da2022-12-22T03:52:04ZengElsevierData in Brief2352-34092019-08-0125In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworksAram L. Bugaev0Alina A. Skorynina1Elizaveta G. Kamyshova2Kirill A. Lomachenko3Alexander A. Guda4Alexander V. Soldatov5Carlo Lamberti6The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, Russia; Corresponding author.The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, RussiaThe Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, RussiaEuropean Synchrotron Radiation Facility, 71 Avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, FranceThe Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, RussiaThe Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, RussiaThe Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090, Rostov-on-Don, Russia; Department of Physics and CrisDi Interdepartmental Centre, University of Turin, Via P. Giuria 1, 10125 Turin, ItalyWe report a series of Pd K-edge and Pt L3-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at different beamlines, normalized XAS spectra and k2-weighted oscillatory χ(k) functions extracted from one of the datasets. Pd K-edge spectra were collected for the samples in 5% H2/He, 3% H2/He and pure He in the temperature range from room temperature (RT) to 450 °C. Pt L3-edge were collected for the samples in 3% H2/He, 10% H2/He and pure He in the temperature range from RT to 300 °C. All spectra are reported together with the used atmosphere and temperature. For the analysis of all reported datasets, please see “Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks”. Fourier-analysis of Pd K-edge is reported in “Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS”. Keywords: EXAFS, XANES, MOFs, Nanoparticleshttp://www.sciencedirect.com/science/article/pii/S2352340919306341 |
| spellingShingle | Aram L. Bugaev Alina A. Skorynina Elizaveta G. Kamyshova Kirill A. Lomachenko Alexander A. Guda Alexander V. Soldatov Carlo Lamberti In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks Data in Brief |
| title | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
| title_full | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
| title_fullStr | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
| title_full_unstemmed | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
| title_short | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
| title_sort | in situ x ray absorption spectroscopy data during formation of active pt and pd sites in functionalized uio 67 metal organic frameworks |
| url | http://www.sciencedirect.com/science/article/pii/S2352340919306341 |
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