Electrochromic properties of monosubstituted benzylboronic acid viologen
Synthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow...
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EDP Sciences
2023-01-01
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Series: | MATEC Web of Conferences |
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Online Access: | https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdf |
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author | Tang Shengwei Niu Junlong Jia Chunyang |
author_facet | Tang Shengwei Niu Junlong Jia Chunyang |
author_sort | Tang Shengwei |
collection | DOAJ |
description | Synthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow down the diffusion rate and effectively mitigate viologen dimerization, which may address the issues caused by dimerization. The optical contrasts of mBBV and mBBV-PVA reached 49.02% and 45.01%, respectively. The electrochemical and electrochromic properties obtained from the tests suggest the potential application of mBBV in the field of electrochromics. |
first_indexed | 2024-03-12T22:39:59Z |
format | Article |
id | doaj.art-0fd1afd016424f8a8f73bbed95fc47ae |
institution | Directory Open Access Journal |
issn | 2261-236X |
language | English |
last_indexed | 2024-03-12T22:39:59Z |
publishDate | 2023-01-01 |
publisher | EDP Sciences |
record_format | Article |
series | MATEC Web of Conferences |
spelling | doaj.art-0fd1afd016424f8a8f73bbed95fc47ae2023-07-21T09:55:58ZengEDP SciencesMATEC Web of Conferences2261-236X2023-01-013820100310.1051/matecconf/202338201003matecconf_amme2023_01003Electrochromic properties of monosubstituted benzylboronic acid viologenTang Shengwei0Niu Junlong1Jia Chunyang2State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaState Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaState Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaSynthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow down the diffusion rate and effectively mitigate viologen dimerization, which may address the issues caused by dimerization. The optical contrasts of mBBV and mBBV-PVA reached 49.02% and 45.01%, respectively. The electrochemical and electrochromic properties obtained from the tests suggest the potential application of mBBV in the field of electrochromics.https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdfelectrochromicall-in-oneboronic ester linkagesviologen |
spellingShingle | Tang Shengwei Niu Junlong Jia Chunyang Electrochromic properties of monosubstituted benzylboronic acid viologen MATEC Web of Conferences electrochromic all-in-one boronic ester linkages viologen |
title | Electrochromic properties of monosubstituted benzylboronic acid viologen |
title_full | Electrochromic properties of monosubstituted benzylboronic acid viologen |
title_fullStr | Electrochromic properties of monosubstituted benzylboronic acid viologen |
title_full_unstemmed | Electrochromic properties of monosubstituted benzylboronic acid viologen |
title_short | Electrochromic properties of monosubstituted benzylboronic acid viologen |
title_sort | electrochromic properties of monosubstituted benzylboronic acid viologen |
topic | electrochromic all-in-one boronic ester linkages viologen |
url | https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdf |
work_keys_str_mv | AT tangshengwei electrochromicpropertiesofmonosubstitutedbenzylboronicacidviologen AT niujunlong electrochromicpropertiesofmonosubstitutedbenzylboronicacidviologen AT jiachunyang electrochromicpropertiesofmonosubstitutedbenzylboronicacidviologen |