Electrochromic properties of monosubstituted benzylboronic acid viologen

Synthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow...

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Main Authors: Tang Shengwei, Niu Junlong, Jia Chunyang
Format: Article
Language:English
Published: EDP Sciences 2023-01-01
Series:MATEC Web of Conferences
Subjects:
Online Access:https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdf
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author Tang Shengwei
Niu Junlong
Jia Chunyang
author_facet Tang Shengwei
Niu Junlong
Jia Chunyang
author_sort Tang Shengwei
collection DOAJ
description Synthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow down the diffusion rate and effectively mitigate viologen dimerization, which may address the issues caused by dimerization. The optical contrasts of mBBV and mBBV-PVA reached 49.02% and 45.01%, respectively. The electrochemical and electrochromic properties obtained from the tests suggest the potential application of mBBV in the field of electrochromics.
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spelling doaj.art-0fd1afd016424f8a8f73bbed95fc47ae2023-07-21T09:55:58ZengEDP SciencesMATEC Web of Conferences2261-236X2023-01-013820100310.1051/matecconf/202338201003matecconf_amme2023_01003Electrochromic properties of monosubstituted benzylboronic acid viologenTang Shengwei0Niu Junlong1Jia Chunyang2State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaState Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaState Key Laboratory of Electronic Thin Films and Integrated Devices, School of Integrated Circuit Science and Engineering, University of Electronic Science and Technology of ChinaSynthesis of monosubstituted benzyl boronic acid viologen (mBBV) has been achieved. The boronic acid group in mBBV can form boronic ester bonds with the hydroxyl groups in polyvinyl alcohol (PVA), resulting in an all-in-one electrochromic gel. The immobilized viologen by boronic ester bonds can slow down the diffusion rate and effectively mitigate viologen dimerization, which may address the issues caused by dimerization. The optical contrasts of mBBV and mBBV-PVA reached 49.02% and 45.01%, respectively. The electrochemical and electrochromic properties obtained from the tests suggest the potential application of mBBV in the field of electrochromics.https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdfelectrochromicall-in-oneboronic ester linkagesviologen
spellingShingle Tang Shengwei
Niu Junlong
Jia Chunyang
Electrochromic properties of monosubstituted benzylboronic acid viologen
MATEC Web of Conferences
electrochromic
all-in-one
boronic ester linkages
viologen
title Electrochromic properties of monosubstituted benzylboronic acid viologen
title_full Electrochromic properties of monosubstituted benzylboronic acid viologen
title_fullStr Electrochromic properties of monosubstituted benzylboronic acid viologen
title_full_unstemmed Electrochromic properties of monosubstituted benzylboronic acid viologen
title_short Electrochromic properties of monosubstituted benzylboronic acid viologen
title_sort electrochromic properties of monosubstituted benzylboronic acid viologen
topic electrochromic
all-in-one
boronic ester linkages
viologen
url https://www.matec-conferences.org/articles/matecconf/pdf/2023/09/matecconf_amme2023_01003.pdf
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