Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments

Polycyclic aromatic hydrocarbons (PAHs) are among the important organic pollutants in the aquatic ecosystems generally generated by natural and human processes. The purpose of this study was to determine the concentration and distribution of PAHs and the origin of these compounds in the surface sedi...

Full description

Bibliographic Details
Main Authors: Azita Behbahaninia, Alireza Mashayekhi, Ali Azimi
Format: Article
Language:fas
Published: Iranian Rainwater Catchment Systems Association 2021-10-01
Series:محیط زیست و مهندسی آب
Subjects:
Online Access:http://www.jewe.ir/article_128567_05f2e1c3bbba687d2b388aa7cfd9c469.pdf
_version_ 1797783493341609984
author Azita Behbahaninia
Alireza Mashayekhi
Ali Azimi
author_facet Azita Behbahaninia
Alireza Mashayekhi
Ali Azimi
author_sort Azita Behbahaninia
collection DOAJ
description Polycyclic aromatic hydrocarbons (PAHs) are among the important organic pollutants in the aquatic ecosystems generally generated by natural and human processes. The purpose of this study was to determine the concentration and distribution of PAHs and the origin of these compounds in the surface sediments of the Protected Chalous River in Mazandaran Province. Sampling of surface sediments of the riverbed was performed at four stations located along the river (Darkala, first ring bridge, Chalous fountain bridge and estuary). The extraction and analysis of PAHs was performed using standard Soxhlet method in two stages: column chromatography and gas chromatography-mass spectrometry. The highest and lowest total amount of these compounds (∑PAHs) was observed in the surface sediments of the riverbed at the estuary and Darkala stations (903.8±144.30 and 51.71±19.33 ng/g) respectively. The trend of accumulation of PAHs in the surface sediments showed that the ∑PAHs concentration increased from the upstream to downstream in the river. Determining the origin of PAHs in surface sediments of the riverbed using isomeric diagnostic ratios showed that the origin of PAHs in the river was a mixture of petrogenic and pyrogenic sources with petrogenic dominance. According to the NOAA sediment quality standard, the sediments samples were in the range of moderate pollution in the studied stations, except at Darkala station, located upstream of Chalous river and had low pollution. The influx of agricultural effluents from the surrounding farms, the increase in population and vehicles in the area has led to an increase in the composition of PAHs in river sediments.
first_indexed 2024-03-13T00:26:43Z
format Article
id doaj.art-0fd86232608046bfb4af49e6472d93bd
institution Directory Open Access Journal
issn 2476-3683
language fas
last_indexed 2024-03-13T00:26:43Z
publishDate 2021-10-01
publisher Iranian Rainwater Catchment Systems Association
record_format Article
series محیط زیست و مهندسی آب
spelling doaj.art-0fd86232608046bfb4af49e6472d93bd2023-07-11T04:46:59ZfasIranian Rainwater Catchment Systems Associationمحیط زیست و مهندسی آب2476-36832021-10-017344445310.22034/jewe.2021.267103.1500128567Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface SedimentsAzita Behbahaninia0Alireza Mashayekhi1Ali Azimi2Assist. Professor, Department of Environment, Faculty of Agriculture, Islamic Azad University, Roudhan Branch, Roudhan, IranM.Sc., Department of Environment, Faculty of Environment and Natural Resource, Islamic Azad University, Science and Research Branch, Tehran, IranPhD Alumni, Iran Fisheries Organization, Tehran, IranPolycyclic aromatic hydrocarbons (PAHs) are among the important organic pollutants in the aquatic ecosystems generally generated by natural and human processes. The purpose of this study was to determine the concentration and distribution of PAHs and the origin of these compounds in the surface sediments of the Protected Chalous River in Mazandaran Province. Sampling of surface sediments of the riverbed was performed at four stations located along the river (Darkala, first ring bridge, Chalous fountain bridge and estuary). The extraction and analysis of PAHs was performed using standard Soxhlet method in two stages: column chromatography and gas chromatography-mass spectrometry. The highest and lowest total amount of these compounds (∑PAHs) was observed in the surface sediments of the riverbed at the estuary and Darkala stations (903.8±144.30 and 51.71±19.33 ng/g) respectively. The trend of accumulation of PAHs in the surface sediments showed that the ∑PAHs concentration increased from the upstream to downstream in the river. Determining the origin of PAHs in surface sediments of the riverbed using isomeric diagnostic ratios showed that the origin of PAHs in the river was a mixture of petrogenic and pyrogenic sources with petrogenic dominance. According to the NOAA sediment quality standard, the sediments samples were in the range of moderate pollution in the studied stations, except at Darkala station, located upstream of Chalous river and had low pollution. The influx of agricultural effluents from the surrounding farms, the increase in population and vehicles in the area has led to an increase in the composition of PAHs in river sediments.http://www.jewe.ir/article_128567_05f2e1c3bbba687d2b388aa7cfd9c469.pdfchalous riversurface sedimentoriginpahs
spellingShingle Azita Behbahaninia
Alireza Mashayekhi
Ali Azimi
Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
محیط زیست و مهندسی آب
chalous river
surface sediment
origin
pahs
title Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
title_full Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
title_fullStr Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
title_full_unstemmed Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
title_short Investigation of Distribution and Origin of Polycyclic Aromatic Hydrocarbons (PAHs) in Chalous River Surface Sediments
title_sort investigation of distribution and origin of polycyclic aromatic hydrocarbons pahs in chalous river surface sediments
topic chalous river
surface sediment
origin
pahs
url http://www.jewe.ir/article_128567_05f2e1c3bbba687d2b388aa7cfd9c469.pdf
work_keys_str_mv AT azitabehbahaninia investigationofdistributionandoriginofpolycyclicaromatichydrocarbonspahsinchalousriversurfacesediments
AT alirezamashayekhi investigationofdistributionandoriginofpolycyclicaromatichydrocarbonspahsinchalousriversurfacesediments
AT aliazimi investigationofdistributionandoriginofpolycyclicaromatichydrocarbonspahsinchalousriversurfacesediments