| Summary: | BackgroundFeCrAl alloy cladding, as an accident tolerant fuel (ATF) mid-term commercial technology approach, has received extensive attention.PurposeThis study aims to investigate the effect of trace Y on the internal pressure burst and oxidation properties of FeCrAl alloy cladding.MethodsFirstly, the crystalline grain size and micro-morphologies of FeCrAl and FeCrAlY alloy cladding samples were observed by optical microscope. Internal pressure burst and high temperature oxidation tests were carried out by burst test equipment and thermo-gravimetric analyzer with a moisture generator. Then, X-ray diffractometry (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS) were employed to analyze the composition of oxidation products, surface and cross-sectional micro-morphologies of FeCrAl and FeCrAlY alloy cladding samples before and after high-temperature stream oxidation and the distribution of elements on the surface oxidation products.ResultsThe results show that trace Y is mainly dissolved in the FeCrAl alloy matrix, and no Fe-Y phase is formed. The inclusion of Y do not change the burst strength and the rupture opening morphology at room temperature (RT) to 1 000 ℃, and the high-temperature steam oxidation resistance of FeCrAl alloy cladding is significantly improved by the trace Y. Under the condition of steam oxidation at 800 ℃, 1 000 ℃ and 1 200 °C for 8 h, the oxidation weight gain of FeCrAlY alloy cladding decrease by 65.1%, 60.0% and 31.5%, respectively. Compared with the single Al2O3 oxide film on the surface of FeCrAl alloy cladding, the Y-containing composite oxide film with lower internal stress, higher compactness and better adhesion with the substrate is formed on the surface of FeCrAlY alloy cladding.ConclusionsTherefore, the addition of trace Y do not change the burst properties of FeCrAl alloy cladding, however, the high-temperature steam oxidation resistance of FeCrAl alloy cladding is significantly improved.
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