Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry
In the extensive terrain of catalytic procedures for the synthesis of organic molecules, metal–organic frameworks (MOFs) as heterogenous catalysts have been investigated in a variety of chemical processes, including Friedel–Crafts reactions, condensation reactions, oxidations, and coupling reactions...
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| Format: | Article |
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MDPI AG
2023-01-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/13/1/130 |
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| author | Riddima Singh Gurleen Singh Nancy George Gurjaspreet Singh Sofia Gupta Harminder Singh Gurpreet Kaur Jandeep Singh |
| author_facet | Riddima Singh Gurleen Singh Nancy George Gurjaspreet Singh Sofia Gupta Harminder Singh Gurpreet Kaur Jandeep Singh |
| author_sort | Riddima Singh |
| collection | DOAJ |
| description | In the extensive terrain of catalytic procedures for the synthesis of organic molecules, metal–organic frameworks (MOFs) as heterogenous catalysts have been investigated in a variety of chemical processes, including Friedel–Crafts reactions, condensation reactions, oxidations, and coupling reactions, and utilized owing to their specific properties such as high porosity, tuneability, extraordinary catalytic activity, and recyclability. The eminent copper-tailored MOF materials can be exceptionally dynamic and regioselective catalysts for click reactions (1,3-dipolar cycloaddition reaction). Considering the fact that Cu(I)-catalyzed alkyne–azide cycloaddition (CuAAC) reactions can be catalyzed by several other copper catalysts such as Cu (II)-β-cyclodextrin, Cu(OAc)<sub>2</sub>, Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>, picolinimidoamide–Cu(II) complex, and Cu(II) porphyrin graphene, the properties of sorption and reusability, as well as the high density of copper-MOFs, open an efficient and robust pathway for regimented catalysis of this reaction. This review provides a comprehensive description and analysis of the relevant literature on the utilization of Cu-MOFs as catalysts for CuAAC ‘click’ reactions published in the past decade. |
| first_indexed | 2024-03-09T13:14:13Z |
| format | Article |
| id | doaj.art-10060ede8b2a430599c8b10c228c76f5 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-09T13:14:13Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-10060ede8b2a430599c8b10c228c76f52023-11-30T21:37:43ZengMDPI AGCatalysts2073-43442023-01-0113113010.3390/catal13010130Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click ChemistryRiddima Singh0Gurleen Singh1Nancy George2Gurjaspreet Singh3Sofia Gupta4Harminder Singh5Gurpreet Kaur6Jandeep Singh7School of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara 144411, IndiaSchool of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara 144411, IndiaSchool of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara 144411, IndiaDepartment of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, IndiaDepartment of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, IndiaSchool of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara 144411, IndiaDepartment of Chemistry, Gujranwala Guru Nanak Khalsa College, Civil Lines, Ludhiana 141001, IndiaSchool of Chemical Engineering and Physical Sciences, Lovely Professional University, Phagwara 144411, IndiaIn the extensive terrain of catalytic procedures for the synthesis of organic molecules, metal–organic frameworks (MOFs) as heterogenous catalysts have been investigated in a variety of chemical processes, including Friedel–Crafts reactions, condensation reactions, oxidations, and coupling reactions, and utilized owing to their specific properties such as high porosity, tuneability, extraordinary catalytic activity, and recyclability. The eminent copper-tailored MOF materials can be exceptionally dynamic and regioselective catalysts for click reactions (1,3-dipolar cycloaddition reaction). Considering the fact that Cu(I)-catalyzed alkyne–azide cycloaddition (CuAAC) reactions can be catalyzed by several other copper catalysts such as Cu (II)-β-cyclodextrin, Cu(OAc)<sub>2</sub>, Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>, picolinimidoamide–Cu(II) complex, and Cu(II) porphyrin graphene, the properties of sorption and reusability, as well as the high density of copper-MOFs, open an efficient and robust pathway for regimented catalysis of this reaction. This review provides a comprehensive description and analysis of the relevant literature on the utilization of Cu-MOFs as catalysts for CuAAC ‘click’ reactions published in the past decade.https://www.mdpi.com/2073-4344/13/1/130metal–organic frameworks (MOF)Cu-MOFcatalyst1,4-disubstituted 1,2,3-triazoleclick chemistryheterogenous catalysis |
| spellingShingle | Riddima Singh Gurleen Singh Nancy George Gurjaspreet Singh Sofia Gupta Harminder Singh Gurpreet Kaur Jandeep Singh Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry Catalysts metal–organic frameworks (MOF) Cu-MOF catalyst 1,4-disubstituted 1,2,3-triazole click chemistry heterogenous catalysis |
| title | Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry |
| title_full | Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry |
| title_fullStr | Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry |
| title_full_unstemmed | Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry |
| title_short | Copper-Based Metal–Organic Frameworks (MOFs) as an Emerging Catalytic Framework for Click Chemistry |
| title_sort | copper based metal organic frameworks mofs as an emerging catalytic framework for click chemistry |
| topic | metal–organic frameworks (MOF) Cu-MOF catalyst 1,4-disubstituted 1,2,3-triazole click chemistry heterogenous catalysis |
| url | https://www.mdpi.com/2073-4344/13/1/130 |
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