Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance

The lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into t...

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Main Authors: Jolanta Drabik, Kamil Korasiak, Justyna Chrobak, Julia Woch, Natalia Brzeźniak, Wioletta Barszcz, Rafał Kozdrach, Jolanta Iłowska
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/1/122
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author Jolanta Drabik
Kamil Korasiak
Justyna Chrobak
Julia Woch
Natalia Brzeźniak
Wioletta Barszcz
Rafał Kozdrach
Jolanta Iłowska
author_facet Jolanta Drabik
Kamil Korasiak
Justyna Chrobak
Julia Woch
Natalia Brzeźniak
Wioletta Barszcz
Rafał Kozdrach
Jolanta Iłowska
author_sort Jolanta Drabik
collection DOAJ
description The lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into the oils and greases was highly effective in slowing down the oxidation process. Lubricants containing mono–15 ([3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylbuthylamine)propyl]hexadecanamide chloride) and 15–4–15 (tetramethylene-bis [3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylamine)propyl]hexadecanamide) additives were characterised by higher oxidation stability compared to the unmodified lubricants. Both of the analysed substances showed bactericidal properties against <i>Staphylococcus aureus</i> and <i>Salmonella enteritica</i>. Tests of antibacterial activity in the lubricants with the addition of mono–15 and 15–4–15 confirmed that these lubricants can be considered bactericidal against Gram-positive and Gram-negative bacteria.
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spelling doaj.art-10094c85a37a48c2b388b34c4e4814912024-01-10T15:04:13ZengMDPI AGMolecules1420-30492023-12-0129112210.3390/molecules29010122Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear ResistanceJolanta Drabik0Kamil Korasiak1Justyna Chrobak2Julia Woch3Natalia Brzeźniak4Wioletta Barszcz5Rafał Kozdrach6Jolanta Iłowska7Łukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandThe lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into the oils and greases was highly effective in slowing down the oxidation process. Lubricants containing mono–15 ([3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylbuthylamine)propyl]hexadecanamide chloride) and 15–4–15 (tetramethylene-bis [3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylamine)propyl]hexadecanamide) additives were characterised by higher oxidation stability compared to the unmodified lubricants. Both of the analysed substances showed bactericidal properties against <i>Staphylococcus aureus</i> and <i>Salmonella enteritica</i>. Tests of antibacterial activity in the lubricants with the addition of mono–15 and 15–4–15 confirmed that these lubricants can be considered bactericidal against Gram-positive and Gram-negative bacteria.https://www.mdpi.com/1420-3049/29/1/122lubricantsantibacterial propertiesanti-wear propertiesoxidation stability
spellingShingle Jolanta Drabik
Kamil Korasiak
Justyna Chrobak
Julia Woch
Natalia Brzeźniak
Wioletta Barszcz
Rafał Kozdrach
Jolanta Iłowska
Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
Molecules
lubricants
antibacterial properties
anti-wear properties
oxidation stability
title Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
title_full Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
title_fullStr Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
title_full_unstemmed Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
title_short Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
title_sort amide amino based functional additives for lubricants structure antimicrobial activity and wear resistance
topic lubricants
antibacterial properties
anti-wear properties
oxidation stability
url https://www.mdpi.com/1420-3049/29/1/122
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