Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance
The lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into t...
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MDPI AG
2023-12-01
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author | Jolanta Drabik Kamil Korasiak Justyna Chrobak Julia Woch Natalia Brzeźniak Wioletta Barszcz Rafał Kozdrach Jolanta Iłowska |
author_facet | Jolanta Drabik Kamil Korasiak Justyna Chrobak Julia Woch Natalia Brzeźniak Wioletta Barszcz Rafał Kozdrach Jolanta Iłowska |
author_sort | Jolanta Drabik |
collection | DOAJ |
description | The lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into the oils and greases was highly effective in slowing down the oxidation process. Lubricants containing mono–15 ([3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylbuthylamine)propyl]hexadecanamide chloride) and 15–4–15 (tetramethylene-bis [3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylamine)propyl]hexadecanamide) additives were characterised by higher oxidation stability compared to the unmodified lubricants. Both of the analysed substances showed bactericidal properties against <i>Staphylococcus aureus</i> and <i>Salmonella enteritica</i>. Tests of antibacterial activity in the lubricants with the addition of mono–15 and 15–4–15 confirmed that these lubricants can be considered bactericidal against Gram-positive and Gram-negative bacteria. |
first_indexed | 2024-03-08T15:01:02Z |
format | Article |
id | doaj.art-10094c85a37a48c2b388b34c4e481491 |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-08T15:01:02Z |
publishDate | 2023-12-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-10094c85a37a48c2b388b34c4e4814912024-01-10T15:04:13ZengMDPI AGMolecules1420-30492023-12-0129112210.3390/molecules29010122Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear ResistanceJolanta Drabik0Kamil Korasiak1Justyna Chrobak2Julia Woch3Natalia Brzeźniak4Wioletta Barszcz5Rafał Kozdrach6Jolanta Iłowska7Łukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandŁukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute for Sustainable Technologies, 26-600 Radom, PolandŁukasiewicz Research Network–Institute of Heavy Organic Synthesis “Blachownia”, 47-225 Kędzierzyn-Koźle, PolandThe lubricating properties of the lubricants were tested under boundary friction conditions; it was found that the surface-active additives had reduced the wear mark and thus the value of the Goz/40 parameter (limiting load of wear). The introduction of a surfactant containing amide compounds into the oils and greases was highly effective in slowing down the oxidation process. Lubricants containing mono–15 ([3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylbuthylamine)propyl]hexadecanamide chloride) and 15–4–15 (tetramethylene-bis [3-(<i>N</i>,<i>N</i>,<i>N</i>-dimethylamine)propyl]hexadecanamide) additives were characterised by higher oxidation stability compared to the unmodified lubricants. Both of the analysed substances showed bactericidal properties against <i>Staphylococcus aureus</i> and <i>Salmonella enteritica</i>. Tests of antibacterial activity in the lubricants with the addition of mono–15 and 15–4–15 confirmed that these lubricants can be considered bactericidal against Gram-positive and Gram-negative bacteria.https://www.mdpi.com/1420-3049/29/1/122lubricantsantibacterial propertiesanti-wear propertiesoxidation stability |
spellingShingle | Jolanta Drabik Kamil Korasiak Justyna Chrobak Julia Woch Natalia Brzeźniak Wioletta Barszcz Rafał Kozdrach Jolanta Iłowska Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance Molecules lubricants antibacterial properties anti-wear properties oxidation stability |
title | Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance |
title_full | Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance |
title_fullStr | Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance |
title_full_unstemmed | Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance |
title_short | Amide/Amino-Based Functional Additives for Lubricants: Structure, Antimicrobial Activity and Wear Resistance |
title_sort | amide amino based functional additives for lubricants structure antimicrobial activity and wear resistance |
topic | lubricants antibacterial properties anti-wear properties oxidation stability |
url | https://www.mdpi.com/1420-3049/29/1/122 |
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