Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks

This study used the diethylene triamine pentaacetic acid (DTPA)-seawater (SW) system to modify the sandstone rock wettability and enhance oil recovery. The investigation involved conducting wettability measurement, Zeta potential measurement, and spontaneous imbibition experiment. The introduction o...

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Main Authors: Mahsa PARHIZGAR KERADEH, Seyyed Alireza TABATABAEI-NEZHAD
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2023-06-01
Series:Petroleum Exploration and Development
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1876380423604197
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author Mahsa PARHIZGAR KERADEH
Seyyed Alireza TABATABAEI-NEZHAD
author_facet Mahsa PARHIZGAR KERADEH
Seyyed Alireza TABATABAEI-NEZHAD
author_sort Mahsa PARHIZGAR KERADEH
collection DOAJ
description This study used the diethylene triamine pentaacetic acid (DTPA)-seawater (SW) system to modify the sandstone rock wettability and enhance oil recovery. The investigation involved conducting wettability measurement, Zeta potential measurement, and spontaneous imbibition experiment. The introduction of 5% DTPA-SW solution resulted in a significant decrease in the rock-oil contact angle from 143° to 23°, along with a reduction in the Zeta potential from −2.29 mV to −13.06 mV, thereby altering the rock surface charge and shifting its wettability from an oil-wet state to a strongly water-wet state. The presence or absence of potential determining ions (Ca2+, Mg2+, SO42−) in the solution did not impact the effectiveness of DTPA in changing the rock wettability. However, by tripling the concentration of these ions in the solution, the performance of 5% DTPA-SW solution in changing wettability was impaired. Additionally, spontaneous imbibition tests demonstrated that the 5% DTPA-SW solution led to an increase in oil recovery up to 39.6%. Thus, the optimum mass fraction of DTPA for changing sandstone wettability was determined to be 5%.
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spelling doaj.art-100d34076b014f9fb6888a752a7fc9862023-06-16T05:09:12ZengKeAi Communications Co., Ltd.Petroleum Exploration and Development1876-38042023-06-01503675687Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocksMahsa PARHIZGAR KERADEH0Seyyed Alireza TABATABAEI-NEZHAD1Faculty of Petroleum and Natural Gas Engineering, Sahand University of Technology, Tabriz 51335-1996, IranCorresponding author; Faculty of Petroleum and Natural Gas Engineering, Sahand University of Technology, Tabriz 51335-1996, IranThis study used the diethylene triamine pentaacetic acid (DTPA)-seawater (SW) system to modify the sandstone rock wettability and enhance oil recovery. The investigation involved conducting wettability measurement, Zeta potential measurement, and spontaneous imbibition experiment. The introduction of 5% DTPA-SW solution resulted in a significant decrease in the rock-oil contact angle from 143° to 23°, along with a reduction in the Zeta potential from −2.29 mV to −13.06 mV, thereby altering the rock surface charge and shifting its wettability from an oil-wet state to a strongly water-wet state. The presence or absence of potential determining ions (Ca2+, Mg2+, SO42−) in the solution did not impact the effectiveness of DTPA in changing the rock wettability. However, by tripling the concentration of these ions in the solution, the performance of 5% DTPA-SW solution in changing wettability was impaired. Additionally, spontaneous imbibition tests demonstrated that the 5% DTPA-SW solution led to an increase in oil recovery up to 39.6%. Thus, the optimum mass fraction of DTPA for changing sandstone wettability was determined to be 5%.http://www.sciencedirect.com/science/article/pii/S1876380423604197wettability alterationDTPA chelating agentZeta potentialspontaneous imbibitionenhanced oil recovery
spellingShingle Mahsa PARHIZGAR KERADEH
Seyyed Alireza TABATABAEI-NEZHAD
Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
Petroleum Exploration and Development
wettability alteration
DTPA chelating agent
Zeta potential
spontaneous imbibition
enhanced oil recovery
title Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
title_full Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
title_fullStr Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
title_full_unstemmed Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
title_short Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
title_sort investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
topic wettability alteration
DTPA chelating agent
Zeta potential
spontaneous imbibition
enhanced oil recovery
url http://www.sciencedirect.com/science/article/pii/S1876380423604197
work_keys_str_mv AT mahsaparhizgarkeradeh investigationoftheeffectofdiethylenetriaminepentaaceticacidchelatingagentasanenhancedoilrecoveryfluidonwettabilityalterationofsandstonerocks
AT seyyedalirezatabatabaeinezhad investigationoftheeffectofdiethylenetriaminepentaaceticacidchelatingagentasanenhancedoilrecoveryfluidonwettabilityalterationofsandstonerocks