Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites

The materials currently used for bone prostheses are mainly metals such as titanium alloy. Compared with human cortical bone, traditional metals exhibit high elastic moduli, which may lead to stress shielding. In contrast, the mechanical strength and elastic modulus of polyetheretherketone are sligh...

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Main Authors: Lijian Liu, Yongkang Zhang, Shaobo Ma, Shouxiao Zhu, Shuxuan Wu, Bin Wei, Guang Yang
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/14/5/1723
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author Lijian Liu
Yongkang Zhang
Shaobo Ma
Shouxiao Zhu
Shuxuan Wu
Bin Wei
Guang Yang
author_facet Lijian Liu
Yongkang Zhang
Shaobo Ma
Shouxiao Zhu
Shuxuan Wu
Bin Wei
Guang Yang
author_sort Lijian Liu
collection DOAJ
description The materials currently used for bone prostheses are mainly metals such as titanium alloy. Compared with human cortical bone, traditional metals exhibit high elastic moduli, which may lead to stress shielding. In contrast, the mechanical strength and elastic modulus of polyetheretherketone are slightly lower than those of human bone. In this study, we utilize multi-component co-modification in order to improve the mechanical properties of polyetheretherketone materials. Firstly, we blended three types of materials: multi-walled carbon nanotubes, nanohydroxyapatite, and carbon fibers. Then, the blended materials were used to reinforce polyetheretherketone, and the preparation of the multi-walled carbon nanotubes/nanohydroxyapatite/carbon fibers was described in detail. After the contact angle was determined, SEM, thermogravimetric analysis, and various tests were conducted on the ternary composites. Ball milling co-mingling technology was used to prepare tetrad composite specimens for tensile and compression experiments, a finite element model of the tetrad composite tensile and compression specimens was established, and the structural stresses of the specimens were analyzed under the specified loads. The experimental results show that the surface roughness of carbon fiber increased, and the multi-walled carbon nanotube/nanohydroxyapatite/carbon fiber/polyetheretherketone quaternary composites were well optimized in terms of strength and elastic modulus, which broadens the application field of polyetheretherketone materials.
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spelling doaj.art-101f7dc75f0d479aaf51afede85ed9d42024-03-12T16:38:39ZengMDPI AGApplied Sciences2076-34172024-02-01145172310.3390/app14051723Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone CompositesLijian Liu0Yongkang Zhang1Shaobo Ma2Shouxiao Zhu3Shuxuan Wu4Bin Wei5Guang Yang6College of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaCollege of Mechanical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, ChinaThe materials currently used for bone prostheses are mainly metals such as titanium alloy. Compared with human cortical bone, traditional metals exhibit high elastic moduli, which may lead to stress shielding. In contrast, the mechanical strength and elastic modulus of polyetheretherketone are slightly lower than those of human bone. In this study, we utilize multi-component co-modification in order to improve the mechanical properties of polyetheretherketone materials. Firstly, we blended three types of materials: multi-walled carbon nanotubes, nanohydroxyapatite, and carbon fibers. Then, the blended materials were used to reinforce polyetheretherketone, and the preparation of the multi-walled carbon nanotubes/nanohydroxyapatite/carbon fibers was described in detail. After the contact angle was determined, SEM, thermogravimetric analysis, and various tests were conducted on the ternary composites. Ball milling co-mingling technology was used to prepare tetrad composite specimens for tensile and compression experiments, a finite element model of the tetrad composite tensile and compression specimens was established, and the structural stresses of the specimens were analyzed under the specified loads. The experimental results show that the surface roughness of carbon fiber increased, and the multi-walled carbon nanotube/nanohydroxyapatite/carbon fiber/polyetheretherketone quaternary composites were well optimized in terms of strength and elastic modulus, which broadens the application field of polyetheretherketone materials.https://www.mdpi.com/2076-3417/14/5/1723multi-walled carbon nanotubesnanohydroxyapatitecarbon fiberpolyetheretherketonefinite element analysis
spellingShingle Lijian Liu
Yongkang Zhang
Shaobo Ma
Shouxiao Zhu
Shuxuan Wu
Bin Wei
Guang Yang
Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
Applied Sciences
multi-walled carbon nanotubes
nanohydroxyapatite
carbon fiber
polyetheretherketone
finite element analysis
title Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
title_full Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
title_fullStr Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
title_full_unstemmed Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
title_short Preparation and Characterization of High-Strength and High-Modulus Multi-Walled Carbon Nanotube/Hydroxyapatite/Carbon Fiber/Polyetheretherketone Composites
title_sort preparation and characterization of high strength and high modulus multi walled carbon nanotube hydroxyapatite carbon fiber polyetheretherketone composites
topic multi-walled carbon nanotubes
nanohydroxyapatite
carbon fiber
polyetheretherketone
finite element analysis
url https://www.mdpi.com/2076-3417/14/5/1723
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