Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations
A convenient synthetic approach to meso-substituted with 2,2’-bipyridine and 1-(pyridin-2-yl)isoquinoline residues calix[4]arenes is reported. This approach involves the reaction of generated in situ 2-lithio-calix[4]arene with 1,2,4-triazine precursor with the following aromatization of the obtaine...
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| Format: | Article |
| Language: | English |
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Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2020-12-01
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| Series: | Chimica Techno Acta |
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| Online Access: | https://journals.urfu.ru/index.php/chimtech/article/view/4655 |
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| author | T. D. Moseev A. F. Khasanov M. V. Varaksin D. S. Kopchuk I. S. Kovalev O. S. Taniya M. Rahman S. Santra G. V. Zyryanov O. N. Chupakhin V. N. Charushin |
| author_facet | T. D. Moseev A. F. Khasanov M. V. Varaksin D. S. Kopchuk I. S. Kovalev O. S. Taniya M. Rahman S. Santra G. V. Zyryanov O. N. Chupakhin V. N. Charushin |
| author_sort | T. D. Moseev |
| collection | DOAJ |
| description | A convenient synthetic approach to meso-substituted with 2,2’-bipyridine and 1-(pyridin-2-yl)isoquinoline residues calix[4]arenes is reported. This approach involves the reaction of generated in situ 2-lithio-calix[4]arene with 1,2,4-triazine precursor with the following aromatization of the obtained adduct, and the aza-Diels-Alder reaction of the 1,2,4-triazinyl-substituted calix[4]arene with 2,5-norbornadien or in-situ generated 1,2-dehydrobenzene. The UV/fluorescence response of thus obtained meso-pyridyl-substituted calix[4]arenes to metal cations is studied. |
| first_indexed | 2024-12-22T20:22:08Z |
| format | Article |
| id | doaj.art-1034844306454201b1fe4c019ae2e580 |
| institution | Directory Open Access Journal |
| issn | 2411-1414 |
| language | English |
| last_indexed | 2024-12-22T20:22:08Z |
| publishDate | 2020-12-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj.art-1034844306454201b1fe4c019ae2e5802022-12-21T18:13:49ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142020-12-017421522110.15826/chimtech.2020.7.4.143717Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cationsT. D. Moseev0A. F. Khasanov1M. V. Varaksin2D. S. Kopchuk3I. S. Kovalev4O. S. Taniya5M. Rahman6S. Santra7G. V. Zyryanov8O. N. Chupakhin9V. N. Charushin10Ural Federal University, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, EkaterinburgUral Federal University, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgUral Federal University, Ekaterinburg; I.Ya. Postovsky Institute of Organic Synthesis of RAS, EkaterinburgA convenient synthetic approach to meso-substituted with 2,2’-bipyridine and 1-(pyridin-2-yl)isoquinoline residues calix[4]arenes is reported. This approach involves the reaction of generated in situ 2-lithio-calix[4]arene with 1,2,4-triazine precursor with the following aromatization of the obtained adduct, and the aza-Diels-Alder reaction of the 1,2,4-triazinyl-substituted calix[4]arene with 2,5-norbornadien or in-situ generated 1,2-dehydrobenzene. The UV/fluorescence response of thus obtained meso-pyridyl-substituted calix[4]arenes to metal cations is studied.https://journals.urfu.ru/index.php/chimtech/article/view/4655calix[4]arene1,2,4-triazinesaza-diels-alder reaction2,2’-bipyridinesvisual cations detection |
| spellingShingle | T. D. Moseev A. F. Khasanov M. V. Varaksin D. S. Kopchuk I. S. Kovalev O. S. Taniya M. Rahman S. Santra G. V. Zyryanov O. N. Chupakhin V. N. Charushin Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations Chimica Techno Acta calix[4]arene 1,2,4-triazines aza-diels-alder reaction 2,2’-bipyridines visual cations detection |
| title | Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations |
| title_full | Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations |
| title_fullStr | Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations |
| title_full_unstemmed | Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations |
| title_short | Synthesis of meso-2,2’-bipyridyl-substituted calix[4]arenes and their response to metal cations |
| title_sort | synthesis of meso 2 2 bipyridyl substituted calix 4 arenes and their response to metal cations |
| topic | calix[4]arene 1,2,4-triazines aza-diels-alder reaction 2,2’-bipyridines visual cations detection |
| url | https://journals.urfu.ru/index.php/chimtech/article/view/4655 |
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