Halides as versatile anions in asymmetric anion-binding organocatalysis
This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2021-09-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.17.145 |
| _version_ | 1819242904685641728 |
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| author | Lukas Schifferer Martin Stinglhamer Kirandeep Kaur Olga García Macheño |
| author_facet | Lukas Schifferer Martin Stinglhamer Kirandeep Kaur Olga García Macheño |
| author_sort | Lukas Schifferer |
| collection | DOAJ |
| description | This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst–anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional noncovalent contacts within the HB-donor catalyst and supramolecular interactions to both the anion and the cationic reactive species. |
| first_indexed | 2024-12-23T14:47:13Z |
| format | Article |
| id | doaj.art-103c3820b6c043d9970692429dc3f27f |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-23T14:47:13Z |
| publishDate | 2021-09-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-103c3820b6c043d9970692429dc3f27f2022-12-21T17:43:03ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972021-09-011712270228610.3762/bjoc.17.1451860-5397-17-145Halides as versatile anions in asymmetric anion-binding organocatalysisLukas Schifferer0Martin Stinglhamer1Kirandeep Kaur2Olga García Macheño3Organic Chemistry Institute, Westfälische-Wilhelms University Münster, Correnstraße 36, 48149 Münster, GermanyOrganic Chemistry Institute, Westfälische-Wilhelms University Münster, Correnstraße 36, 48149 Münster, GermanyOrganic Chemistry Institute, Westfälische-Wilhelms University Münster, Correnstraße 36, 48149 Münster, GermanyOrganic Chemistry Institute, Westfälische-Wilhelms University Münster, Correnstraße 36, 48149 Münster, GermanyThis review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst–anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional noncovalent contacts within the HB-donor catalyst and supramolecular interactions to both the anion and the cationic reactive species.https://doi.org/10.3762/bjoc.17.145anion bindingasymmetric catalysishalide anionshydrogen donorsnoncovalent interactions |
| spellingShingle | Lukas Schifferer Martin Stinglhamer Kirandeep Kaur Olga García Macheño Halides as versatile anions in asymmetric anion-binding organocatalysis Beilstein Journal of Organic Chemistry anion binding asymmetric catalysis halide anions hydrogen donors noncovalent interactions |
| title | Halides as versatile anions in asymmetric anion-binding organocatalysis |
| title_full | Halides as versatile anions in asymmetric anion-binding organocatalysis |
| title_fullStr | Halides as versatile anions in asymmetric anion-binding organocatalysis |
| title_full_unstemmed | Halides as versatile anions in asymmetric anion-binding organocatalysis |
| title_short | Halides as versatile anions in asymmetric anion-binding organocatalysis |
| title_sort | halides as versatile anions in asymmetric anion binding organocatalysis |
| topic | anion binding asymmetric catalysis halide anions hydrogen donors noncovalent interactions |
| url | https://doi.org/10.3762/bjoc.17.145 |
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