Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives

Conductive polymer poly-3-hexylthiophene (P3HT) needles were self-assembled using a second component (indandione derivatives) as a linking agent to enhance their long range alignment. The morphologies of the hybrid organic/organic materials were characterized by transmission electron microscopy (TEM...

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Main Authors: Amir Fahmi, Neil Shirtcliffe, Clifford Fowkes, Nicolas Cheval, Valdis Kampars
Format: Article
Language:English
Published: MDPI AG 2013-02-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/3/1/107
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author Amir Fahmi
Neil Shirtcliffe
Clifford Fowkes
Nicolas Cheval
Valdis Kampars
author_facet Amir Fahmi
Neil Shirtcliffe
Clifford Fowkes
Nicolas Cheval
Valdis Kampars
author_sort Amir Fahmi
collection DOAJ
description Conductive polymer poly-3-hexylthiophene (P3HT) needles were self-assembled using a second component (indandione derivatives) as a linking agent to enhance their long range alignment. The morphologies of the hybrid organic/organic materials were characterized by transmission electron microscopy (TEM). Both linear and branched structures could be produced, with the degree of branching depending upon the linker used. Incorporation of indandione derivatives broadened the UV absorbance band of P3HT without significant change to its photoluminescence. This hybrid material could open a promising avenue in photovoltaic applications due to its interesting morphologies and optical properties.
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spelling doaj.art-103fbe319ec945fabc1af00068cab1602022-12-21T21:51:52ZengMDPI AGNanomaterials2079-49912013-02-013110711610.3390/nano3010107Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione DerivativesAmir FahmiNeil ShirtcliffeClifford FowkesNicolas ChevalValdis KamparsConductive polymer poly-3-hexylthiophene (P3HT) needles were self-assembled using a second component (indandione derivatives) as a linking agent to enhance their long range alignment. The morphologies of the hybrid organic/organic materials were characterized by transmission electron microscopy (TEM). Both linear and branched structures could be produced, with the degree of branching depending upon the linker used. Incorporation of indandione derivatives broadened the UV absorbance band of P3HT without significant change to its photoluminescence. This hybrid material could open a promising avenue in photovoltaic applications due to its interesting morphologies and optical properties.http://www.mdpi.com/2079-4991/3/1/107poly-3-hexylthiophenedirected self-assemblyindandione derivativesnanofibers
spellingShingle Amir Fahmi
Neil Shirtcliffe
Clifford Fowkes
Nicolas Cheval
Valdis Kampars
Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
Nanomaterials
poly-3-hexylthiophene
directed self-assembly
indandione derivatives
nanofibers
title Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
title_full Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
title_fullStr Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
title_full_unstemmed Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
title_short Assembl y of Poly-3-Hexylthiophene Nano-Crystallites into Low Dimensional Structures Using Indandione Derivatives
title_sort assembl y of poly 3 hexylthiophene nano crystallites into low dimensional structures using indandione derivatives
topic poly-3-hexylthiophene
directed self-assembly
indandione derivatives
nanofibers
url http://www.mdpi.com/2079-4991/3/1/107
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AT cliffordfowkes assemblyofpoly3hexylthiophenenanocrystallitesintolowdimensionalstructuresusingindandionederivatives
AT nicolascheval assemblyofpoly3hexylthiophenenanocrystallitesintolowdimensionalstructuresusingindandionederivatives
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