Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists b...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040549 |
| _version_ | 1819281360569761792 |
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| author | Dayu Wu |
| author_facet | Dayu Wu |
| author_sort | Dayu Wu |
| collection | DOAJ |
| description | In the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists between the methanol solvent molecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K. |
| first_indexed | 2024-12-24T00:58:27Z |
| format | Article |
| id | doaj.art-1046ead92d954dc19e77de438b3262a2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:58:27Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1046ead92d954dc19e77de438b3262a22022-12-21T17:23:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1340m134010.1107/S1600536809040549Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvateDayu WuIn the title complex, [Fe(C12H8N3O2)2]ClO4·CH3OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridylcarbonyl)pyridine-2-carboximidate (bpca) ligands and exhibits a distorted octahedral coordination by six bpca N atoms. A classical O—H...O hydrogen bond exists between the methanol solvent molecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K.http://scripts.iucr.org/cgi-bin/paper?S1600536809040549 |
| spellingShingle | Dayu Wu Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate Acta Crystallographica Section E |
| title | Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate |
| title_full | Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate |
| title_fullStr | Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate |
| title_full_unstemmed | Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate |
| title_short | Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate |
| title_sort | bis n 2 pyridylcarbonyl pyridine 2 carboximidato iron iii perchlorate methanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809040549 |
| work_keys_str_mv | AT dayuwu bisn2pyridylcarbonylpyridine2carboximidatoironiiiperchloratemethanolsolvate |