Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures
Deep Eutectic Solvent (DES)-like mixtures, based on glycerol and different halide organic and inorganic salts, are successfully exploited as new media in copper-free halodediazoniation of arenediazonium salts. The reactions are carried out in absence of metal-based catalysts, at room temperature and...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/6/1909 |
| _version_ | 1797444276653654016 |
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| author | Giovanni Ghigo Matteo Bonomo Achille Antenucci Chiara Reviglio Stefano Dughera |
| author_facet | Giovanni Ghigo Matteo Bonomo Achille Antenucci Chiara Reviglio Stefano Dughera |
| author_sort | Giovanni Ghigo |
| collection | DOAJ |
| description | Deep Eutectic Solvent (DES)-like mixtures, based on glycerol and different halide organic and inorganic salts, are successfully exploited as new media in copper-free halodediazoniation of arenediazonium salts. The reactions are carried out in absence of metal-based catalysts, at room temperature and in a short time. Pure target products are obtained without the need for chromatographic separation. The solvents are fully characterized, and a computational study is presented aiming to understand the reaction mechanism. |
| first_indexed | 2024-03-09T13:09:17Z |
| format | Article |
| id | doaj.art-105d37c64b2e4eb9b2daf61aa335d477 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T13:09:17Z |
| publishDate | 2022-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-105d37c64b2e4eb9b2daf61aa335d4772023-11-30T21:43:06ZengMDPI AGMolecules1420-30492022-03-01276190910.3390/molecules27061909Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like MixturesGiovanni Ghigo0Matteo Bonomo1Achille Antenucci2Chiara Reviglio3Stefano Dughera4Department of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, ItalyDepartment of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, ItalyDepartment of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, ItalyDepartment of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, ItalyDepartment of Chemistry, University of Turin, Via Pietro Giuria 7, 10125 Turin, ItalyDeep Eutectic Solvent (DES)-like mixtures, based on glycerol and different halide organic and inorganic salts, are successfully exploited as new media in copper-free halodediazoniation of arenediazonium salts. The reactions are carried out in absence of metal-based catalysts, at room temperature and in a short time. Pure target products are obtained without the need for chromatographic separation. The solvents are fully characterized, and a computational study is presented aiming to understand the reaction mechanism.https://www.mdpi.com/1420-3049/27/6/1909Sandmeyer reactionsdeep eutectic solventsreaction mechanism |
| spellingShingle | Giovanni Ghigo Matteo Bonomo Achille Antenucci Chiara Reviglio Stefano Dughera Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures Molecules Sandmeyer reactions deep eutectic solvents reaction mechanism |
| title | Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures |
| title_full | Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures |
| title_fullStr | Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures |
| title_full_unstemmed | Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures |
| title_short | Copper-Free Halodediazoniation of Arenediazonium Tetrafluoroborates in Deep Eutectic Solvents-like Mixtures |
| title_sort | copper free halodediazoniation of arenediazonium tetrafluoroborates in deep eutectic solvents like mixtures |
| topic | Sandmeyer reactions deep eutectic solvents reaction mechanism |
| url | https://www.mdpi.com/1420-3049/27/6/1909 |
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