Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone
Catalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived b...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2020-10-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/50558 |
| _version_ | 1818853783915986944 |
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| author | Fahri Swasdika Wega Trisunaryanti Iip Izul Falah |
| author_facet | Fahri Swasdika Wega Trisunaryanti Iip Izul Falah |
| author_sort | Fahri Swasdika |
| collection | DOAJ |
| description | Catalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived bio-oil. The wet impregnation was performed by directly dispersing Cu(NO3)2·3H2O and/or Zn(NO3)2·4H2O aqueous solution into MSA, followed by calcination and reduction under H2 gas stream. The acidity test revealed that metal addition on MSA support increases the acidity of catalysts. During hydrotreatment of cellulose-derived bio-oil CuZn/MSA with total acidity, copper loading, zinc loading, and specific surface area of 24.86 mmol g–1, 5.23 wt.%, 3.15 wt.%, and 170.77 m2 g–1, respectively, exhibited the best performance compared to other prepared catalysts with 90.49 wt.% conversion of liquid product. |
| first_indexed | 2024-12-19T07:42:19Z |
| format | Article |
| id | doaj.art-10649fcb8f7a491d822401d13c42659c |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-12-19T07:42:19Z |
| publishDate | 2020-10-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-10649fcb8f7a491d822401d13c42659c2022-12-21T20:30:25ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782020-10-0121226827810.22146/ijc.5055828534Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish BoneFahri Swasdika0Wega Trisunaryanti1Iip Izul Falah2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaCatalysts comprising copper and/or zinc supported on mesoporous silica-alumina (MSA) with a high Si/Al ratio were prepared by wet impregnation method. This study investigated the preparation, characterization, and catalytic application of the prepared catalysts for hydrotreatment cellulose-derived bio-oil. The wet impregnation was performed by directly dispersing Cu(NO3)2·3H2O and/or Zn(NO3)2·4H2O aqueous solution into MSA, followed by calcination and reduction under H2 gas stream. The acidity test revealed that metal addition on MSA support increases the acidity of catalysts. During hydrotreatment of cellulose-derived bio-oil CuZn/MSA with total acidity, copper loading, zinc loading, and specific surface area of 24.86 mmol g–1, 5.23 wt.%, 3.15 wt.%, and 170.77 m2 g–1, respectively, exhibited the best performance compared to other prepared catalysts with 90.49 wt.% conversion of liquid product.https://jurnal.ugm.ac.id/ijc/article/view/50558hydrotreatmentbio-oilcatalysisbifunctional catalystmesoporous silica-alumina |
| spellingShingle | Fahri Swasdika Wega Trisunaryanti Iip Izul Falah Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone Indonesian Journal of Chemistry hydrotreatment bio-oil catalysis bifunctional catalyst mesoporous silica-alumina |
| title | Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone |
| title_full | Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone |
| title_fullStr | Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone |
| title_full_unstemmed | Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone |
| title_short | Hydrotreatment of Cellulose-Derived Bio-Oil Using Copper and/or Zinc Catalysts Supported on Mesoporous Silica-Alumina Synthesized from Lapindo Mud and Catfish Bone |
| title_sort | hydrotreatment of cellulose derived bio oil using copper and or zinc catalysts supported on mesoporous silica alumina synthesized from lapindo mud and catfish bone |
| topic | hydrotreatment bio-oil catalysis bifunctional catalyst mesoporous silica-alumina |
| url | https://jurnal.ugm.ac.id/ijc/article/view/50558 |
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