Anticorrosion behavior of bioemulsions on metal-environment interface
The influence of Ricinus communis oil on electrochemical corrosion of steel in oil-in-water emulsions under controlled hydrodynamic condition was investigated. Emulsions from renewable biobased sources have gained prominent role in food and pharmaceutical industries as green excipients. The emulsion...
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Elsevier
2023-01-01
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Series: | Results in Chemistry |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715623000978 |
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author | D. Geetha B. Selvakumar M. Velayutham Pillai S. Arunachalam |
author_facet | D. Geetha B. Selvakumar M. Velayutham Pillai S. Arunachalam |
author_sort | D. Geetha |
collection | DOAJ |
description | The influence of Ricinus communis oil on electrochemical corrosion of steel in oil-in-water emulsions under controlled hydrodynamic condition was investigated. Emulsions from renewable biobased sources have gained prominent role in food and pharmaceutical industries as green excipients. The emulsion system under study was prepared from ricinus communis oil, hexadecyl polyglucoside and brine solution in which ricinus communis oil constitute the non-polar phase and surfactant constitute polar phase. The efficiency and effectiveness of these emulsion system highly influenced by their constituents and composition. Thus the stability of the as-prepared emulsion is analyzed through the optimization of various emulsion formulation factors such as viscosity, and creaming rate. The stability of emulsion was observed to increase with viscosity since it makes the particles to distribute evenly. The application of the emulsion on metallic surface under controlled hydrodynamic conditions was studied using potentiodynamic polarization Tafal plots. The newly formulated emulsion showed corrosion inhibition on the tested alloy steel and their corrosion rate was reduced to 0.5598 mm/year.The antimicrobial activity of this versatile emulsion was also assessed using in-vitro assay. This emulsion formulation can be used economically in industrial application as it may reduce the preventive maintenance, replacement of corroded equipment and contamination of product. |
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id | doaj.art-1068e5882d3d491083ee53e74d9de62e |
institution | Directory Open Access Journal |
issn | 2211-7156 |
language | English |
last_indexed | 2024-03-13T04:13:11Z |
publishDate | 2023-01-01 |
publisher | Elsevier |
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series | Results in Chemistry |
spelling | doaj.art-1068e5882d3d491083ee53e74d9de62e2023-06-21T06:52:17ZengElsevierResults in Chemistry2211-71562023-01-015100858Anticorrosion behavior of bioemulsions on metal-environment interfaceD. Geetha0B. Selvakumar1M. Velayutham Pillai2S. Arunachalam3Department of Chemistry, Kalasalingam Academy of Research and Education, Srivilliputhur 626126, IndiaDepartment of Physics, Sri Eshwar College of Engineering, Coimbatore, Tamil Nadu 641023, IndiaDepartment of Chemistry, NGM College, Pollachi, Tamil Nadu 642001, IndiaDepartment of Electrochemistry, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai 602105, India; Corresponding author.The influence of Ricinus communis oil on electrochemical corrosion of steel in oil-in-water emulsions under controlled hydrodynamic condition was investigated. Emulsions from renewable biobased sources have gained prominent role in food and pharmaceutical industries as green excipients. The emulsion system under study was prepared from ricinus communis oil, hexadecyl polyglucoside and brine solution in which ricinus communis oil constitute the non-polar phase and surfactant constitute polar phase. The efficiency and effectiveness of these emulsion system highly influenced by their constituents and composition. Thus the stability of the as-prepared emulsion is analyzed through the optimization of various emulsion formulation factors such as viscosity, and creaming rate. The stability of emulsion was observed to increase with viscosity since it makes the particles to distribute evenly. The application of the emulsion on metallic surface under controlled hydrodynamic conditions was studied using potentiodynamic polarization Tafal plots. The newly formulated emulsion showed corrosion inhibition on the tested alloy steel and their corrosion rate was reduced to 0.5598 mm/year.The antimicrobial activity of this versatile emulsion was also assessed using in-vitro assay. This emulsion formulation can be used economically in industrial application as it may reduce the preventive maintenance, replacement of corroded equipment and contamination of product.http://www.sciencedirect.com/science/article/pii/S2211715623000978Ricinoleic acidCorrosion potentialOil-in-water emulsionCorrosion inhibition |
spellingShingle | D. Geetha B. Selvakumar M. Velayutham Pillai S. Arunachalam Anticorrosion behavior of bioemulsions on metal-environment interface Results in Chemistry Ricinoleic acid Corrosion potential Oil-in-water emulsion Corrosion inhibition |
title | Anticorrosion behavior of bioemulsions on metal-environment interface |
title_full | Anticorrosion behavior of bioemulsions on metal-environment interface |
title_fullStr | Anticorrosion behavior of bioemulsions on metal-environment interface |
title_full_unstemmed | Anticorrosion behavior of bioemulsions on metal-environment interface |
title_short | Anticorrosion behavior of bioemulsions on metal-environment interface |
title_sort | anticorrosion behavior of bioemulsions on metal environment interface |
topic | Ricinoleic acid Corrosion potential Oil-in-water emulsion Corrosion inhibition |
url | http://www.sciencedirect.com/science/article/pii/S2211715623000978 |
work_keys_str_mv | AT dgeetha anticorrosionbehaviorofbioemulsionsonmetalenvironmentinterface AT bselvakumar anticorrosionbehaviorofbioemulsionsonmetalenvironmentinterface AT mvelayuthampillai anticorrosionbehaviorofbioemulsionsonmetalenvironmentinterface AT sarunachalam anticorrosionbehaviorofbioemulsionsonmetalenvironmentinterface |