Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate
The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C20H21NO8·C2H6O. The title molecule comprises a fused tricyclic system containing two five-membered rings (cyclopentane and tetrahydrofuran)...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809045528 |
| _version_ | 1818999159755112448 |
|---|---|
| author | Victor N. Khrustalev Vladimir P. Zaytsev Inga K. Airiyan Atash V. Gurbanov Eugeniya V. Nikitina |
| author_facet | Victor N. Khrustalev Vladimir P. Zaytsev Inga K. Airiyan Atash V. Gurbanov Eugeniya V. Nikitina |
| author_sort | Victor N. Khrustalev |
| collection | DOAJ |
| description | The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C20H21NO8·C2H6O. The title molecule comprises a fused tricyclic system containing two five-membered rings (cyclopentane and tetrahydrofuran) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation. |
| first_indexed | 2024-12-20T22:13:00Z |
| format | Article |
| id | doaj.art-106955c084294c68a30e5c6e6c0d27d6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:13:00Z |
| publishDate | 2009-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-106955c084294c68a30e5c6e6c0d27d62022-12-21T19:25:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512o2981o298110.1107/S1600536809045528Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvateVictor N. KhrustalevVladimir P. ZaytsevInga K. AiriyanAtash V. GurbanovEugeniya V. NikitinaThe title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C20H21NO8·C2H6O. The title molecule comprises a fused tricyclic system containing two five-membered rings (cyclopentane and tetrahydrofuran) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536809045528 |
| spellingShingle | Victor N. Khrustalev Vladimir P. Zaytsev Inga K. Airiyan Atash V. Gurbanov Eugeniya V. Nikitina Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate Acta Crystallographica Section E |
| title | Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate |
| title_full | Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate |
| title_fullStr | Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate |
| title_full_unstemmed | Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate |
| title_short | Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate |
| title_sort | methyl 4 5 diacetoxy 1 oxo 2 phenylperhydro 4 6 epoxycyclopenta c pyridine 7 carboxylate ethanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809045528 |
| work_keys_str_mv | AT victornkhrustalev methyl45diacetoxy1oxo2phenylperhydro46epoxycyclopentacpyridine7carboxylateethanolsolvate AT vladimirpzaytsev methyl45diacetoxy1oxo2phenylperhydro46epoxycyclopentacpyridine7carboxylateethanolsolvate AT ingakairiyan methyl45diacetoxy1oxo2phenylperhydro46epoxycyclopentacpyridine7carboxylateethanolsolvate AT atashvgurbanov methyl45diacetoxy1oxo2phenylperhydro46epoxycyclopentacpyridine7carboxylateethanolsolvate AT eugeniyavnikitina methyl45diacetoxy1oxo2phenylperhydro46epoxycyclopentacpyridine7carboxylateethanolsolvate |