The origin of extrathermodynamic compensations

The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their...

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Bibliographic Details
Main Authors: Oleg A. Khakhel', Tamila P. Romashko
Format: Article
Language:English
Published: Elsevier 2019-06-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844019329184
Description
Summary:The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of pyrene excimers.
ISSN:2405-8440