Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)]
The N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(CH3COO)2(NO3)4], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O ato...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809055743 |
| _version_ | 1818791588797612032 |
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| author | Yousef Fazaeli Mostafa M. Amini Seik Weng Ng |
| author_facet | Yousef Fazaeli Mostafa M. Amini Seik Weng Ng |
| author_sort | Yousef Fazaeli |
| collection | DOAJ |
| description | The N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(CH3COO)2(NO3)4], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N—H groups form intramolecular N—H...O hydrogen bonds. One of the nitrate ions is disordered over two positions in a 0.80 (3):0.20 (3) occupancy ratio. |
| first_indexed | 2024-12-18T15:13:45Z |
| format | Article |
| id | doaj.art-10902570d3184fc7bb3ed3d326cc7286 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:13:45Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-10902570d3184fc7bb3ed3d326cc72862022-12-21T21:03:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m163m16310.1107/S1600536809055743Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)]Yousef FazaeliMostafa M. AminiSeik Weng NgThe N-heterocycles in the centrosymmetric title compound, [La2(C10H9NO)4(CH3COO)2(NO3)4], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N—H groups form intramolecular N—H...O hydrogen bonds. One of the nitrate ions is disordered over two positions in a 0.80 (3):0.20 (3) occupancy ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536809055743 |
| spellingShingle | Yousef Fazaeli Mostafa M. Amini Seik Weng Ng Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] Acta Crystallographica Section E |
| title | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] |
| title_full | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] |
| title_fullStr | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] |
| title_full_unstemmed | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] |
| title_short | Bis(μ-2-methyl-8-oxidoquinolin-1-ium-κ2O:O)bis[(acetato-κ2O,O′)(2-methyl-8-oxidoquinolin-1-ium-κO)bis(nitrato-κ2O,O′)lanthanum(III)] |
| title_sort | bis amp 956 2 methyl 8 oxidoquinolin 1 ium amp 954 2o o bis acetato amp 954 2o o amp 8242 2 methyl 8 oxidoquinolin 1 ium amp 954 o bis nitrato amp 954 2o o amp 8242 lanthanum iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809055743 |
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