Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)

Here, we report a design strategy for constructing supramolecular organic frameworks by introducing <sup>1</sup>H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple <sup>1</sup>H-pyrazole [N−H···N] hydrogen b...

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Main Authors: Ji Wang, Li-Rong Zhao, Jin Tong, Yan-Min Yu, Xia-Yan Wang, Shu-Yan Yu
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/23/8/4206
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author Ji Wang
Li-Rong Zhao
Jin Tong
Yan-Min Yu
Xia-Yan Wang
Shu-Yan Yu
author_facet Ji Wang
Li-Rong Zhao
Jin Tong
Yan-Min Yu
Xia-Yan Wang
Shu-Yan Yu
author_sort Ji Wang
collection DOAJ
description Here, we report a design strategy for constructing supramolecular organic frameworks by introducing <sup>1</sup>H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple <sup>1</sup>H-pyrazole [N−H···N] hydrogen bonds as well as other weak interactions. The new supramolecular organic frameworks displayed interesting crystallization-induced emission (CIE) behavior.
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spelling doaj.art-109611b871dc4c2f8b63bf87f9c0cf812023-12-01T21:02:56ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672022-04-01238420610.3390/ijms23084206Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)Ji Wang0Li-Rong Zhao1Jin Tong2Yan-Min Yu3Xia-Yan Wang4Shu-Yan Yu5Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaCenter of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaCenter of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaCenter of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaCenter of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaCenter of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, ChinaHere, we report a design strategy for constructing supramolecular organic frameworks by introducing <sup>1</sup>H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple <sup>1</sup>H-pyrazole [N−H···N] hydrogen bonds as well as other weak interactions. The new supramolecular organic frameworks displayed interesting crystallization-induced emission (CIE) behavior.https://www.mdpi.com/1422-0067/23/8/4206supramolecular assemblyhydrogen bondingaromatic multi-<sup>1</sup>H-pyrazolescrystallization-induced emission (CIE)
spellingShingle Ji Wang
Li-Rong Zhao
Jin Tong
Yan-Min Yu
Xia-Yan Wang
Shu-Yan Yu
Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
International Journal of Molecular Sciences
supramolecular assembly
hydrogen bonding
aromatic multi-<sup>1</sup>H-pyrazoles
crystallization-induced emission (CIE)
title Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
title_full Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
title_fullStr Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
title_full_unstemmed Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
title_short Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-<sup>1</sup>H-Pyrazoles with Crystallization-Induced Emission (CIE)
title_sort supramolecular hydrogen bonding assembly from non coplanar aromatic tetra sup 1 sup h pyrazoles with crystallization induced emission cie
topic supramolecular assembly
hydrogen bonding
aromatic multi-<sup>1</sup>H-pyrazoles
crystallization-induced emission (CIE)
url https://www.mdpi.com/1422-0067/23/8/4206
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