Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide

The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one MnII ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I− counter-anions. The isolated complex cations have an octahedral configuration and are grouped in hexagonally arranged rows extending parallel to [100]. The two I...

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Main Authors: Mathias Glatz, Martina Schroffenegger, Matthias Weil, Karl Kirchner
Format: Article
Language:English
Published: International Union of Crystallography 2016-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016008896
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author Mathias Glatz
Martina Schroffenegger
Matthias Weil
Karl Kirchner
author_facet Mathias Glatz
Martina Schroffenegger
Matthias Weil
Karl Kirchner
author_sort Mathias Glatz
collection DOAJ
description The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one MnII ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I− counter-anions. The isolated complex cations have an octahedral configuration and are grouped in hexagonally arranged rows extending parallel to [100]. The two I− anions are located between the rows and are linked to the cations through two weak C—H...I interactions.
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spelling doaj.art-10c5ccc09aa245b69b537362b437879f2022-12-22T04:06:03ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-07-0172790490610.1107/S2056989016008896su5305Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodideMathias Glatz0Martina Schroffenegger1Matthias Weil2Karl Kirchner3Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, AustriaInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, AustriaInstitute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, AustriaInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060 Vienna, AustriaThe asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one MnII ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I− counter-anions. The isolated complex cations have an octahedral configuration and are grouped in hexagonally arranged rows extending parallel to [100]. The two I− anions are located between the rows and are linked to the cations through two weak C—H...I interactions.http://scripts.iucr.org/cgi-bin/paper?S2056989016008896crystal structuredimethyl sulfoxidemanganese(II)octahedral coordination
spellingShingle Mathias Glatz
Martina Schroffenegger
Matthias Weil
Karl Kirchner
Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
dimethyl sulfoxide
manganese(II)
octahedral coordination
title Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
title_full Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
title_fullStr Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
title_full_unstemmed Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
title_short Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) diiodide
title_sort crystal structure of hexakis dimethyl sulfoxide κo manganese ii diiodide
topic crystal structure
dimethyl sulfoxide
manganese(II)
octahedral coordination
url http://scripts.iucr.org/cgi-bin/paper?S2056989016008896
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AT martinaschroffenegger crystalstructureofhexakisdimethylsulfoxidekomanganeseiidiiodide
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AT karlkirchner crystalstructureofhexakisdimethylsulfoxidekomanganeseiidiiodide