(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate

In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen...

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Main Authors: Guang-Chuan Ou, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
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author Guang-Chuan Ou
Seik Weng Ng
author_facet Guang-Chuan Ou
Seik Weng Ng
author_sort Guang-Chuan Ou
collection DOAJ
description In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions.
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spelling doaj.art-10c5eb6ab3f2431a89bcc91089fadcbd2022-12-21T17:25:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1468m146810.1107/S1600536810042637(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvateGuang-Chuan OuSeik Weng NgIn the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions.http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
spellingShingle Guang-Chuan Ou
Seik Weng Ng
(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
Acta Crystallographica Section E
title (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_full (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_fullStr (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_full_unstemmed (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_short (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
title_sort 2 carboxyacetato amp 954 2o1 o1 amp 8242 rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 nickel ii perchlorate acetonitrile solvate
url http://scripts.iucr.org/cgi-bin/paper?S1600536810042637
work_keys_str_mv AT guangchuanou 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate
AT seikwengng 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate