(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate
In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810042637 |
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author | Guang-Chuan Ou Seik Weng Ng |
author_facet | Guang-Chuan Ou Seik Weng Ng |
author_sort | Guang-Chuan Ou |
collection | DOAJ |
description | In the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions. |
first_indexed | 2024-12-24T00:04:18Z |
format | Article |
id | doaj.art-10c5eb6ab3f2431a89bcc91089fadcbd |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-24T00:04:18Z |
publishDate | 2010-11-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-10c5eb6ab3f2431a89bcc91089fadcbd2022-12-21T17:25:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1468m146810.1107/S1600536810042637(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvateGuang-Chuan OuSeik Weng NgIn the crystal structure of the title salt, [Ni(C3H3O4)(C16H36N4)]ClO4·CH3CN, the macrocycle folds around the NiII atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N—H...O hydrogen bonds into centrosymmetric dimers. Further N—H...O and O—H...O hydrogen bonds link the complex molecules and the perchlorate ions.http://scripts.iucr.org/cgi-bin/paper?S1600536810042637 |
spellingShingle | Guang-Chuan Ou Seik Weng Ng (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate Acta Crystallographica Section E |
title | (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
title_full | (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
title_fullStr | (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
title_full_unstemmed | (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
title_short | (2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate acetonitrile solvate |
title_sort | 2 carboxyacetato amp 954 2o1 o1 amp 8242 rac 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradecane amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 nickel ii perchlorate acetonitrile solvate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810042637 |
work_keys_str_mv | AT guangchuanou 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate AT seikwengng 2carboxyacetatoamp9542o1o1amp8242rac557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliiperchlorateacetonitrilesolvate |