Plutonium (IV) Quantification in Technologically Relevant Media Using Potentiometric Sensor Array

The quantification of plutonium in technological streams during spent nuclear fuel (SNF) reprocessing is an important practical task that has to be solved to ensure the safety of the process. Currently applied methods are tedious, time-consuming and can hardly be implemented in on-line mode. A fast...

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Bibliographic Details
Main Authors: Julia Savosina, Marina Agafonova-Moroz, Irina Yaroshenko, Julia Ashina, Vasily Babain, Alexander Lumpov, Andrey Legin, Dmitry Kirsanov
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/20/6/1604
Description
Summary:The quantification of plutonium in technological streams during spent nuclear fuel (SNF) reprocessing is an important practical task that has to be solved to ensure the safety of the process. Currently applied methods are tedious, time-consuming and can hardly be implemented in on-line mode. A fast and simple quantitative plutonium (IV) analysis using a potentiometric sensor array based on extracting agents is suggested in this study. The response of the set of specially designed PVC-plasticized membrane sensors can be related to plutonium content in solutions simulating real SNF-reprocessing media through multivariate regression modeling, providing 30% higher precision of plutonium quantification than optical spectroscopy.
ISSN:1424-8220