Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network

In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neig...

Full description

Bibliographic Details
Main Authors: Chia-Hwa Lee, Gene-Hsiang Lee
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016004497
_version_ 1818971595698339840
author Chia-Hwa Lee
Gene-Hsiang Lee
author_facet Chia-Hwa Lee
Gene-Hsiang Lee
author_sort Chia-Hwa Lee
collection DOAJ
description In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.
first_indexed 2024-12-20T14:54:53Z
format Article
id doaj.art-10dea89d487b4a21a399db926e36ca08
institution Directory Open Access Journal
issn 2056-9890
language English
last_indexed 2024-12-20T14:54:53Z
publishDate 2016-04-01
publisher International Union of Crystallography
record_format Article
series Acta Crystallographica Section E: Crystallographic Communications
spelling doaj.art-10dea89d487b4a21a399db926e36ca082022-12-21T19:36:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-04-0172455655810.1107/S2056989016004497bg2582Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding networkChia-Hwa Lee0Gene-Hsiang Lee1Department of Chemistry, National Taiwan University, Taipei, TaiwanInstrumentation Center, National Taiwan University, Taipei, TaiwanIn the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2056989016004497crystal structureimidazole derivativehydrogen bondingsupramolecular architecture
spellingShingle Chia-Hwa Lee
Gene-Hsiang Lee
Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
imidazole derivative
hydrogen bonding
supramolecular architecture
title Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_full Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_fullStr Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_full_unstemmed Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_short Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_sort crystal structure of 1 2 bis 1h imidazol 2 yl methylidene hydrazine and its one dimensional hydrogen bonding network
topic crystal structure
imidazole derivative
hydrogen bonding
supramolecular architecture
url http://scripts.iucr.org/cgi-bin/paper?S2056989016004497
work_keys_str_mv AT chiahwalee crystalstructureof12bis1himidazol2ylmethylidenehydrazineanditsonedimensionalhydrogenbondingnetwork
AT genehsianglee crystalstructureof12bis1himidazol2ylmethylidenehydrazineanditsonedimensionalhydrogenbondingnetwork