Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neig...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2016-04-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016004497 |
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author | Chia-Hwa Lee Gene-Hsiang Lee |
author_facet | Chia-Hwa Lee Gene-Hsiang Lee |
author_sort | Chia-Hwa Lee |
collection | DOAJ |
description | In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction. |
first_indexed | 2024-12-20T14:54:53Z |
format | Article |
id | doaj.art-10dea89d487b4a21a399db926e36ca08 |
institution | Directory Open Access Journal |
issn | 2056-9890 |
language | English |
last_indexed | 2024-12-20T14:54:53Z |
publishDate | 2016-04-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E: Crystallographic Communications |
spelling | doaj.art-10dea89d487b4a21a399db926e36ca082022-12-21T19:36:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-04-0172455655810.1107/S2056989016004497bg2582Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding networkChia-Hwa Lee0Gene-Hsiang Lee1Department of Chemistry, National Taiwan University, Taipei, TaiwanInstrumentation Center, National Taiwan University, Taipei, TaiwanIn the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2056989016004497crystal structureimidazole derivativehydrogen bondingsupramolecular architecture |
spellingShingle | Chia-Hwa Lee Gene-Hsiang Lee Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network Acta Crystallographica Section E: Crystallographic Communications crystal structure imidazole derivative hydrogen bonding supramolecular architecture |
title | Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network |
title_full | Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network |
title_fullStr | Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network |
title_full_unstemmed | Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network |
title_short | Crystal structure of 1,2-bis[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network |
title_sort | crystal structure of 1 2 bis 1h imidazol 2 yl methylidene hydrazine and its one dimensional hydrogen bonding network |
topic | crystal structure imidazole derivative hydrogen bonding supramolecular architecture |
url | http://scripts.iucr.org/cgi-bin/paper?S2056989016004497 |
work_keys_str_mv | AT chiahwalee crystalstructureof12bis1himidazol2ylmethylidenehydrazineanditsonedimensionalhydrogenbondingnetwork AT genehsianglee crystalstructureof12bis1himidazol2ylmethylidenehydrazineanditsonedimensionalhydrogenbondingnetwork |