Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay

Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with different arenes using eco-friendly FeCl3 and K-10 clay under thermal heating was accomplished, in good to excellent yields (66–79%). The methodology was extended to benzaldehyde derived simple MBH adducts als...

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Main Authors: Sivaprakasam Sivaraman, Selvaraj Aruljothi, Vadivel Vaithiyanathan
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Results in Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715622003964
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author Sivaprakasam Sivaraman
Selvaraj Aruljothi
Vadivel Vaithiyanathan
author_facet Sivaprakasam Sivaraman
Selvaraj Aruljothi
Vadivel Vaithiyanathan
author_sort Sivaprakasam Sivaraman
collection DOAJ
description Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with different arenes using eco-friendly FeCl3 and K-10 clay under thermal heating was accomplished, in good to excellent yields (66–79%). The methodology was extended to benzaldehyde derived simple MBH adducts also. The details of the work are elaborately discussed in this letter.
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spelling doaj.art-10fa155112484f29a5634210729c6bfb2022-12-22T03:53:13ZengElsevierResults in Chemistry2211-71562022-01-014100677Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 claySivaprakasam Sivaraman0Selvaraj Aruljothi1Vadivel Vaithiyanathan2Department of Chemistry, Arignar Anna Govt. Arts College, Villupuram (Re-accredited by the NAAC with “B+” and Affiliated to Annamalai University, Chidambaram), Tamilnadu 605 602, IndiaDepartment of Chemistry, Arignar Anna Govt. Arts College, Villupuram (Re-accredited by the NAAC with “B+” and Affiliated to Annamalai University, Chidambaram), Tamilnadu 605 602, IndiaCorresponding author.; Department of Chemistry, Arignar Anna Govt. Arts College, Villupuram (Re-accredited by the NAAC with “B+” and Affiliated to Annamalai University, Chidambaram), Tamilnadu 605 602, IndiaAllylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with different arenes using eco-friendly FeCl3 and K-10 clay under thermal heating was accomplished, in good to excellent yields (66–79%). The methodology was extended to benzaldehyde derived simple MBH adducts also. The details of the work are elaborately discussed in this letter.http://www.sciencedirect.com/science/article/pii/S2211715622003964Isomerisation_1MBH adduct_2Allylation_3Arylation_4C–C bond formation_5
spellingShingle Sivaprakasam Sivaraman
Selvaraj Aruljothi
Vadivel Vaithiyanathan
Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
Results in Chemistry
Isomerisation_1
MBH adduct_2
Allylation_3
Arylation_4
C–C bond formation_5
title Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
title_full Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
title_fullStr Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
title_full_unstemmed Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
title_short Allylic arylative isomerisation of Morita-Baylis-Hillman adduct of isatin derivatives with arenes using FeCl3 and K-10 clay
title_sort allylic arylative isomerisation of morita baylis hillman adduct of isatin derivatives with arenes using fecl3 and k 10 clay
topic Isomerisation_1
MBH adduct_2
Allylation_3
Arylation_4
C–C bond formation_5
url http://www.sciencedirect.com/science/article/pii/S2211715622003964
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AT selvarajaruljothi allylicarylativeisomerisationofmoritabaylishillmanadductofisatinderivativeswitharenesusingfecl3andk10clay
AT vadivelvaithiyanathan allylicarylativeisomerisationofmoritabaylishillmanadductofisatinderivativeswitharenesusingfecl3andk10clay